Surface-stimulated phenomena in the polarization response of ferroelectrics
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A Landau-Ginsburg-Devonshire-type thermodynamic theory is used to describe equilibrium single-domain states and phase transitions in epitaxial ferroelectric thin films. For BaTiO3 and PbTiO3 films grown on cubic substrates, the paraelectric to ferroelectri ...
It was recently suggested, basing on the analysis of a wide range of macroscopic experimental results([1-4]), that fatigue in ferroelectric thin film capacitors, particularly in the case of PZT with metallic electrodes (Pt), must be related to the freezing ...
A phenomenological thermodynamic theory of ferroelectric thin films epitaxially grown on cubic substrates is developed using a new form of the Gibbs function, which corresponds to the actual mechanical boundary conditions of the problem. It is found that t ...
The weak-field dielectric properties of ordered, disordered, and lead-deficient disordered Pb(Sc0.5Ta0.5)O-3 (PST) ceramics (PST-O, PST-D, and PST-DV, respectively) were investigated under various de-bias conditions. The de-bias field influences the parael ...
The pyroelectric properties of Pb1-xCaxTiO3 (x = 0-0.3) thin films have been greatly improved by including porosity in the microstructure. Control of nucleation and growth by variation of the heating rate was used to process porous, low dielectric constant ...
A phase diagram based on dielectric-permittivity-versus-temperature measurements and high-temperature X-ray diffractometry was proposed for 0.4Pb(Ni-1/3,Nb-1/3) O-3-xPbZrO(3)-(0.6-x)PbTiO3, (0.2 less than or equal to x less than or equal to 0.32) relaxor-f ...
Poling of calcium and zirconium modified lead titanate pyroelelectric thin films has been studied, Poling temperature and electrical field were optimized to achieve high figure of merits. It was found that thermal activation is important to obtain highly p ...
PZT thin films for memory applications are known to lack sufficient resistance versus polarization fatigue when used together with platinum. One possible solution for this problem is to use conductive oxides like La1-xSrxCoO3 (LSCO) as an electrode. In thi ...
A surprising non-cumulative effect of the degradation mechanism (fatigue) of the switched polarization (P-r(s)), was observed in MOCVD and sol-gel prepared Pb(Zr0.47Ti0.53)O-3 (PZT) ferroelectric thin films capacitors (FECAP) with Pt-electrodes. This effec ...
Mechanisms of polarization switching and fatigue in (Pb, La)(Zr, Ti)O-3 (PLZT) films are studied by comparative analysis of degradation and leakage conduction of PLZT capacitors with Pt, SrRuO3 (SRO), and layered Pt/SRO (80/5 nm) electrodes. It is found th ...
