Vector modelling of hydrating cement microstructure and kinetics
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Chemical systems with standard reaction enthalpies (ΔH0r) and an activation energies (Ea) of a few tens of kcal/mol are generally well described by the unimolecular reaction rate theory. The goal of this work is to determine the limits of this model by stu ...
This paper investigates the applicability of nucleation and growth mechanisms to the hydration of alite. Various possible mechanisms of nucleation and growth were simulated using the recently-developed microstructural modelling platform mu ic. Comparison w ...
Underground job sites such as tunnels and mines rely on the quality of recently sprayed concrete to secure freshly excavated zones. Rapid setting and early high strength development are required for safety as well as for the rapid progression of the constr ...
A new modelling platform, called mu ic has been developed to model the microstructural evolution of hydrating cement paste. The platform uses the vector approach and can be used for modelling particulate reactions including the hydration of many different ...
Impure tricalcium silicate (Alite, C3S) is the most important and abundant phase of Portland cement. It reacts quickly with water to give calcium hydroxide (CH) and calcium silicate hydrate (C-S-H) which is the most important phase for strength development ...
An important mode of hydration of Ordinary Portland cement (OPC) is via the formation of a shell of hydration products around cement grains. It has been shown so far that shells form not only in OPC but also around C3A grains in a mixture of alite, C3A and ...
The production of Portland cement accounts for 5 to 8% of the global anthropogenic CO2 emissions. In the past years, the cement industry has attempted to reduce this contribution by the use of mineral additions on the cement or in the concrete mix. The typ ...
Hydrated Calcium Aluminate Cement (CAC) is known to have a complex microstructure involving different phase assemblages strongly dependant on the temperature. This work presents an experimental approach to study the microstructure of CAC pastes from the fi ...
During the last 20 years, backscattered electron imaging of polished surfaces has become well established as a method for the study of cement and concrete microstructures. The technique has many advantages, including the visualisation of representative cro ...
Calcium Aluminate Cements (CAC) are renowned in the field of construction for specific applications requiring rapid hardening and chemical resistance. These properties result from rapid exothermic reactions occurring immediately after setting. Due to the m ...
