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The overall aim of this thesis has been to assess the potential of latex-based technologies for the preparation of polymer/clay nanocomposites. The key feature of latex-based technologies is that they offer the possibility of improved control of the final ...
The rheological behavior of two hyperbranched polymer/silica suspensions with different dispersion states, surface chemistries, and concentrations of the silica nanoparticles was investigated in terms of viscoelastic properties, activation energy for visco ...
Bitumen is a complex viscoelastic material used as a binder in applications ranging from road paving to waterproof membranes for roofing [1]. In such applications, bitumen is often blended with a polymer in order to improve its elasticity. The resulting po ...
Wood, like all polymeric materials, shows viscoelastic behaviour. The time dependent behaviour of wood depends on material anisotropy, temperature, moisture and stresses. To predict the behaviour of wood, numerous mathematical models have been developed la ...
This thesis describes measurements of Brownian motion of a colloidal particle using optical trapping. Two aspects are investigated: (i) influence of inertial effects on Brownian motion, and (ii) effect of the optical trap on Brownian motion. The first part ...
The equilibrium dynamics of a spherical particle immersed in a complex Maxwell fluid is analyzed in terms of velocity autocorrelation function (VACF), mean-square displacement (MSD), and power spectral density (PSD). We elucidate the role of hydrodynamic m ...
Polymer materials may exhibit significant viscoelastic behaviour under various type of deformations. A model that can describe various viscous behaviours in simple tension was proposed in a previous work of the laboratory of biomechanical orthopedics. This ...
Polystyrene-based nanocomposite films containing up to 20 wt% laponite clay have been prepared by emulsion polymerization. Significant increases in the storage and tensile moduli were observed in both the glassy and rubbery state on laponite addition. Howe ...
A waterborne latex-based technique, in which functionalized laponite is attached to PS and acrylic latex particles, is used to prepare films containing up to 50 wt% laponite. At high laponite contents this leads to a cellular arrangement of the laponite-ri ...
Organosilicate glasses (OSGs) are used as low-k intermetal dielectrics for advanced integrated circuits. In this application, the material must fulfill two conflicting requirements: It has to have low density to reduce the dielectric constant while being s ...