Studies on the reactivity of organometallic Ru-, Rh- and Os-pta complexes with DNA model compounds
Graph Chatbot
Chattez avec Graph Search
Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.
AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.
The invention relates to a novel class of ligands, complexes comprising such ligands and a metal ion, and adducts of these metal complexes and a macromolecule. Pharmaceutical compositions and methods of making and using the ligand-metal complexes are also ...
A range of coordination and organometallic compounds have been analysed by quadrupole ion-trap mass spectrometry using various photoionisation methods. Atmospheric-pressure photo ionisation (APPI), which combines atmospheric-pressure chemical ionisation (A ...
Liq. chromatog. mass spectrometry (LC-MS) is a valuable tool in the anal. of proteins and peptides. The combination of LC-MS with different fragmentation methods provides sequence information on components in complex mixts. In this work, online packed capi ...
Electrospray ionization mass spectrometry of neat ionic liquids does not require continuous sample injection and the presence of a molecular solvent facilitates analysis of the ionic liquid itself and dissolved analytes. ...
Attachment-induced ionization instability has been experimentally observed in O-2 and CF4 capacitive RF discharges using time-resolved voltage probe, Langmuir probe, optical emission and mass spectrometry measurements. This instability occurs under specifi ...
An (arene)RuCl2 complex with a methacrylate side chain (2) has been prepared in two steps using commercially available starting materials. This complex reacts with PPh3, pyridine, or toluidine to give the corresponding mononuclear adducts (3-5). The s ...
The hydrogenation of benzene and other arenes under aqueous-organic biphasic conditions is evaluated using the ruthenium complexes Ru(eta(6)-C10H14)(pta)Cl-2 (pta=1,3,5-triaza-7-phosphaadamantane), Ru(eta(6)-C10H14)(tppts)Cl-2 (tppts=tris-3-sulfonatophenyl ...
Electron Beam Induced Deposition (EBID) allows deposition of three-dimensional micro- and nano-structures of conductive and insulating materials on a wide range of substrates. The process is based on the decomposition of molecules of a pre-selected precurs ...
The derivatization of neutral transition metal carbonyl clusters with an alkoxide anion, [Mn(CO)xOR]- is discussed. The electrospray ionization mass spectrometry technique is used for the purpose. Control of the potential applied to the skimmer cone of the ...
Liq. sepn. methods in combination with electrospray mass spectrometry as well as the recently introduced fragmentation method electron capture dissocn. (ECD) have become powerful tools in proteomics research. This paper presents the results of the first su ...