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Recent neutron-diffraction studies on dilute solutions have shown that a change in coordination numbers from nine to eight water molecules in the first hydration sphere occurs when going from the light to the heavy lanthanide (III) ions. To acquire a deepe ...
The present invention relates to a new family of mono, bis or tris (2,2'-substituted bipyridine) complexes of a metal selected amongst iron, ruthenium, osmium or vanadium, the bipyridine being substituted by at least one electron donor group. According to ...
We performed variable temperature (0–100°C), concentration and frequency (9.425, 75, 150 and 225 GHz) continuous wave electron paramagnetic resonance (EPR) measurements on three different Gd(III) compounds: [Gd(H2O)8]3+, [Gd(DOTA)(H2O)]− (DOTA: 1,4,7,10-te ...
A new formulation of the current within the London approximation allows the calculation of ring currents in topologically complex molecules. Application of this theory to C60 demonstrates the existence of remarkable pi-electron ring currents. Paramagnetic ...
For the first time, a very general theoretical method is proposed to interpret the full electron paramagnetic resonance (EPR) spectra at multiple temperatures and frequencies in the important case of S-state metal ions complexed in liquid solution. This me ...
