Analysis and study of novel terpolymers composed of acrylamide, mono-charged and double-charged cationic monomers
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Surface-initiated polymerizations represent a versatile toolbox to generate densely grafted assemblies of chain end-tethered polymers. At sufficiently short interchain distances, surface-grafted polymers are forced into an extended chain conformation, whic ...
Amer Chemical Soc2015
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Controlled radical polymerization techniques such as RAFT allow fine control over polymer molecular weight and architecture. These techniques, however, do not eliminate compositional drifts in copolymerizations, which are the consequence of differences in ...
Royal Society of Chemistry2015
Polyelectrolytes (PEL) and PEL complexes formed by electrostatic interaction are recognized as compounds with a remarkable potential for a wide field of applications. However, comprehensive knowledge about electrostatic and structural influences on the pol ...
EPFL2013
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Magnetite nanoparticles are synthesized by thermal decomposition of Fe(acac)(3) and subsequently coated with a silica shell exploiting a water-in-oil synthetic procedure. The as-produced nanopowder is mixed with a photocurable hyperbranched resin and the p ...
2013
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The achievement of high ionic conductivity in single-ion conducting polymer electrolytes is one of the important aims for various electrochemical devices including modern lithium batteries. One way to enhance the ionic conductivity in polyelectrolyte syste ...
2011
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Surface-grafting thermoresponsive polymers allows the preparation of thin polymer brush coatings with surface properties that can be manipulated by variation of temperature. In most instances, thermoresponsive polymer brushes are produced using polymers th ...
Amer Chemical Soc2015
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Previously we reported emulsion polymerization of propylene sulfide with Pluronic F127 as an emulsifier, yielding nanoparticles (NPs) in the 25 nm size range. Immunologically functional NPs were prepared by adding an antigen Pluronic conjugate to the polym ...
2010
During the past decades the field of sensors has been subject to much attention due to an increased demand for (bio)sensors and environmental monitoring. The efforts have been concentrated to create sensors which are reliable, highly sensitive and selectiv ...
EPFL2011
Virus filtration by size exclusion is a robust means of eliminating viruses in blood or pharma products. Porous polymer membranes with a narrow size distribution are used to allow passage of the protein product but retain viruses. The chosen polymer must r ...
2010
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This manuscript reports on the post-polymerization modification of poly(glycidyl methacrylate) (PGMA) and PGMA-co-poly(2-(diethylamino)ethyl methacrylate) (PGMA(x)-co-PDEAEMA(y)) (co)polymer brushes prepared via surface-initiated atom transfer radical poly ...
