2,2’-Bipyrimidine as Efficient Sensitizer of the Solid-State Luminescence of Lanthanide and Uranyl Ions from Visible to Near-Infrared
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The synthesis, structure, and reactivity of stable homoleptic heterometallic LnL(4)K(2) complexes of divalent lanthanide ions with electron-rich tris(tert-butoxy)siloxide ligands are reported. The [Ln(OSi(OtBu)(3))(4)K-2] complexes (Ln=Eu, Yb) are stable a ...
A series of lanthanide complexes Ln(dpxCy)(3) have been synthesised. The ligands are composed of a coordinating dipicolinic acid backbone decorated with a polyoxyethylene arm fitted with a coumarin moiety at its extremity. The nature of the coumarin ...
Luminescent polymer latexes loaded with lanthanide complexes have been synthesized by miniemulsion polymerization. A self-assembled europium complex was embedded into poly(methyl methacrylate) nanoparticles without covalent linking and compared to a commer ...
In the objective of developing ligands that simultaneously satisfy the requirements for MRI contrast agents and near-IR emitting optical probes that are suitable for imaging, three isoquinoline-based polyaminocarboxylate ligands, L1, L2 and L3, have been s ...
A new antenna molecule containing four benzoyltrifluoroacetone (BTFA) moieties anchored to a single carbon atom and connected through four flexible methoxy groups, namely 1,1'-(4,4'-(2,2-bis((4-(4,4,4-trifluoro-3-oxobutanoyl)phenoxy)methyl) propane-1,3-diy ...
A series of novel lanthanide(III) complexes (Ln=Gd, Er, Yb) based on dendritic diphenylquinoxaline (DPQ) ligands was designed and synthesized with the aim of enhancing the luminescence intensity of Er3+ and Yb3+ ions for photonic applications. The diphenyl ...
Photostimulable phosphor CsBr:Eu2+ is prepared through a solid-state reaction. The effect of annealing atmosphere on photoluminescence and photostimulated luminescence was investigated. Optimum luminescence intensity was obtained when samples were prepared ...
New red sesquioxide phosphor, Eu(3+)doped (Y0.5La0.5)(2)O-3, was synthesized in the form of nanocrystalline powder with excellent structural ordering in cubic bixbyite-type, and with nanoparticle sizes ranging between 10 and 20 nm. Photoluminescence measur ...
A hierarchically ordered 4,4'-biphenylene-bridged mesoporous organosilica framework (Bp-PMO) has been synthesized with the aim of using it as a new hybrid host for Ln(III) ions. A series of novel organic-inorganic luminescent hybrid materials have been obt ...
Reaction of Ln(III) with a tetrakis(diketone) ligand H4L [1,1?-(4,4?-(2,2-bis((4-(4,4,4-trifluoro-3-oxobutanoyl) phenoxy)methyl)propane-1,3-diyl)bis(oxy)bis(4,1-phenylene))bis(4,4,4-trifluorobutane-1,3-dione)] gives new podates which, according to mass spe ...