Solvent-Free Ionic Liquid Electrolytes for Mesoscopic Dye-Sensitized Solar Cells
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A model for the design of efficient dyes for p-type dye-sensitized solar cells (DSSCs) is presented. As an example, a novel and efficient org. dye contg. a triphenylamine chromophore was synthesized and applied in a p-type DSSC. An incident photon-to-curre ...
A new metal-free organic sensitizer (see figure) for high-performance and applicable dye-sensitized solar cells is presented. In combination with a solvent-free ionic liquid electrolyte, a similar to 7% cell made with this sensitizer shows all excellent st ...
A series of new hybrid organic-inorganic molecules were prepared either by grafting of aminopropyltriethoxysilane (APTS) on silica nanoparticles followed by quaternarization of the nitrogen with ethyl, heptyl and isopropyl iodides or by grafting of N,N,N-t ...
Five novel perylene mols. with different intramol. charge-transfer (ICT) characters have been synthesized. The relation between the ICT character for different donating groups and the results for their electro- and photochem. properties as well as their pe ...
Dye sensitized solar cells based on annealed titanium dioxide films prepd. by oblique reactive d.c. magnetron sputtering have been investigated. Electron transport and recombination were studied using intensity-modulated photocurrent and photovoltage spect ...
Two org. dyes with the general structure donor-conjugated chain-acceptor (D-π-A) were studied as sensitizers for nanocryst. TiO2 solar cells. The electron donor and acceptor groups were pyrrolidine and cyano acrylic acid, resp. The conjugated chain of 2-cy ...
Nanostructured TiO2 films were modified by insertion with Al ions using an electrochem. process. After heat treatment these films were suitable as electrodes in dye-sensitized solar cells. By a catechol adsorption test and with photoelectron spectroscopy , ...
Novel org. dyes based on the phenothiazine (PTZ) chromophore were designed and synthesized for dye-sensitized solar cells, which give solar energy-to-electricity conversion efficiency (η)of up to 5.5% in comparison with the ref. Ru-complex (N3 dye) with an ...
The authors report on the prepn. of interhalogen ionic liqs. [K+]XY2-, where K+ = 1,3-dialkylimidazolium, 1,2,3-trialkylimidazolium, or N-alkylpyridinium; XY2- = IBr2- or I2Br-. These compds. were characterized in soln. and the solid state by NMR, IR, Rama ...
The transport and recombination of electrons in dye-sensitized TiO2 solar cells were studied by anal. of the current and voltage response to a small square-wave light-intensity modulation. Solar cells were studied under working conditions by using potentio ...