Water adsorption on a sodium smectite clay surface: an ab initio study
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The structure of the title compound, [La(C5H6O4)(C5H7O4)(H2O)] . H2O, consists of dense layers formed by chains of one-edge-sharing LaO9 (H2O) polyhedra, linked together by the glutarate ligand. The three-dimensional polymeric structure, built up through c ...
A low pressure reactor (Knudsen cell) coupled to molecular beam modulated mass spectrometry was used to study the heterogeneous kinetics of the following three systems: (1) NO2 on amorphous carbon, (2) H2O vapor on ice and (3) gaseous HCl on ice. The first ...
Two to four pseudo-generation aliphatic hyperbranched polymers (HBPs) with OH end-groups have been solution processed with various types of montmorillonite (MMT) layered alumino-silicate clays, and carefully dried to produce solid HBP/MMT nanocomposites. ...
Coadsorption of CO and butane on a Pt(533) surface leads to a dynamical system in which both molecules influence the adsorption behavior of each other. Adsorbing butane on a Pt(533) surface with CO on atop step sites leads to tilting of CO molecules of at ...
In this study, we report that intercalation of tin into montmorillonite clay (Sn‐MMT) boosts catalytic activity for the synthesis of polyoxymethylene dimethyl ethers, a promising diesel fuel additive. This increase in activity is attributed to the formatio ...
We propose a new mechanism for the electroreduction of hydrogen in acidic media. The specific model and theoretical calculations are designed for the Pt(111) surface, because this is the only face that exhibits a clear first order phase transition. The bas ...
We discuss our recently proposed mechanism for the electro-oxidation/reduction on Pt(111) surfaces (J. Electroanal. Chem. 2002, 537, 7) in the presence of sulfuric acid. The bisulfate ion has a large dipole moment and is strongly adsorbed on the positive e ...