Oxygen reduction by decamethylferrocene at liquid/liquid interfaces catalyzed by dodecylaniline
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This work contributes to the generalization of the Non-faradaic Electrochemical Modification of Catalytic Activity effect, known under the acronym NEMCA. This effect is observed for the first time over an oxide catalyst, namely IrO2 supported on yttria-sta ...
According to Khan et al. [Khan, A. U., Kovacic, D., Kolbanovskiy, A., Desai, M., Frenkel, K. & Geacintov, N. E. (2000) Proc. Natl. Acad. Sci. USA 97, 2984-2989], peroxynitrite (ONOO(-)) decomposes after protonation to singlet oxygen ((1)Delta(g)O(2)) and s ...
Photoinduced phenomena are of general interest for new materials. Recently, photoinduced molecular desorption of oxygen has been reported in carbon nanotubes. Here we present, using thermopower measurements, that carbon nanotubes when exposed simultaneousl ...
The mechanism of the oxygen redn. reaction (orr) was studied in alk. media at La0.6Ca0.4CoO3-activated carbon electrodes in a channel flow cell (CFC). The electrodes were made by depositing a mixt. of the perovskite (La0.6Ca0.4CoO3) powder as the catalyst, ...
Using a density functional approach, we determine the relative stability of various oxygen species in alpha -quartz. We considered interstitial species in the form of atomic and molecular oxygen, as well as network species, such as peroxyl and ozonyl link- ...
Chemical diffusion (D) and surface exchange (k) coefficients for SrFeO3-delta were measured using an electrochemical cell combined with electrochemical impedance spectroscopy (EIS) and potential step technique (PS) in the temperature range of 850-915°C. A ...
Oxygen is a key substrate in animal cell metab. and its consumption is thus a parameter of great interest for bioprocess monitoring and control. A system for measuring it based on an oxygen balance on the liq. phase was developed. The use of a gas-permeabl ...