The role of calcium and magnesium in the concrete tubes of the sandcastle worm
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This thesis investigates the effect of different parameters such as Fe (III), D-gluconate and heterogeneous particles on the nucleation and growth of synthetic C-S-H by using the dropwise precipitation method. Firstly, the effect of Fe (III) on the synthet ...
This work studies the effect on Embodied Energy (EE) of concrete when Ordinary Portland Cement (OPC) is partially substituted with natural Pozzolanic Volcanic Ash (VA) at the material and the building scale. The work aims to demonstrate potential improveme ...
This paper presents an extension of the graphic-statics-based framework called Combinatorial Equilibrium Modelling (CEM). CEM allows for the generation of topologically and combinatorially different spatial equilibrium solutions in the early explorative de ...
Portland cement has been in use by human civilization for over a century. Yet, we do not fully understand its hydration reaction mechanisms due to the complexity of the system and its continued reaction over time making it hard to study it experimentally. ...
Combination of glass nanocapillaries with optical tweezers allowed us to detect DNA-protein complexes in physiological conditions. In this system, a protein bound to DNA is characterized by a simultaneous change of the force and ionic current signals from ...
Impure tricalcium silicate (C3S) in portland cement may contain various foreign ions. These ions can stabilize different polymorphs of C3S at room temperature and may affect its reactivity. In this paper, the effects of magnesium and zinc on the polymorph ...
A novel clinker with low Ca/Si ratio and low sintering temperature was synthesized, and the property of the clinker was tested. A clinker sintered from industrial raw materials mainly contains rankinite (Ca3Si2O7), pseudowollastonite (Ca-3(Si3O9)) and ferr ...
Experimental evidence shows that the chemical composition of the liquid inside the pores and its variation over time can have significant implications on the mechanical and hydraulic behavior of clayey geomaterials. The magnitude of these implications depe ...
Calcium silicate hydrate (C-S-H) is the main hydrate phase in Portland cements. Its composition
varies depending on the Ca/Si ratio and on the presence of other ions such as aluminium (called CA-
S-H) or alkalis.
This thesis aimed to study the compositi ...