Publication

One or more C-H bond(s) formed by substitution: reduction of carbon-nitrogen, -phosphorus, -arsenic, -antimony, -bismuth, -carbon, -boron and -metal bonds

Publications associées (32)

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Climatic and Ecological Impact of Greenlandic Glacial Outwash Plains

Devis Tuia, Julia Schmale, Nora Bergner, Ianina Altshuler, Gaston Jean Lenczner, Grace Emma Marsh

Warming in the Arctic is occurring at an accelerated rate compared to the rest of the world which is partially driven by ecological and climatic feedback loops. Accelerated glacial and ice sheet retreat in Greenland drives increased development of glacial ...

2023

Metabolic Performance and Fate of Electrons during Nitrate-Reducing Fe(II) Oxidation by the Autotrophic Enrichment Culture KS Grown at Different Initial Fe/N Ratios

Natalia Jakus

Autotrophic nitrate-reducing Fe(II)-oxidizing (NRFeOx) microorganisms fix CO2 and oxidize Fe(II) coupled to denitrification, influencing carbon, iron, and nitrogen cycles in pH-neutral, anoxic environments. However, the distribution of electrons from Fe(II ...

AMER SOC MICROBIOLOGY2023

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

EPFL2022

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The weak carbon-metal bond combined with the kinetic inertness of the carbon-carbon bond renders metal-catalysed C-C bond activation to be highly challenging. Most of the reported C-C bond activation methodologies involve strain-releasing cleavage of small ...

NATURE RESEARCH2021

Lamellar carbon-aluminosilicate nanocomposites with macroscopic orientation

Anna Fontcuberta i Morral, Emad Oveisi, Holger Frauenrath, Enzo Jean Raymond Bomal, Yannik Fontana, Dragana Paripovic

Novel preparative approaches towards lamellar nanocomposites of carbon and inorganic materials are relevant for a broad range of technological applications. Here, we describe how to utilize the co-assembly of a liquid-crystalline hexaphenylene amphiphile a ...

ROYAL SOC CHEMISTRY2021

Kleptoplast distribution, photosynthetic efficiency and sequestration mechanisms in intertidal benthic foraminifera

Anders Meibom, Charlotte Madeleine Nicole Lekieffre, Emmanuelle Geslin, Michael Kühl

Foraminifera are ubiquitously distributed in marine habitats, playing a major role in marine sediment carbon sequestration and the nitrogen cycle. They exhibit a wide diversity of feeding and behavioural strategies (heterotrophy, autotrophy and mixotrophy) ...

SPRINGERNATURE2021

Synthesis of Chiral Cyclopentadienyl Complexes and Applications Towards C-H Functionalization

Benoît Daniel Bertrand Audic

Metal-catalysed C-H bond functionalization has received tremendous attention and developed rapidly over the past decades. Cyclopentadienyl (Cp) metal complexes and their asymmetric counterparts (CpX) are part of a central organometallic category empowering ...

EPFL2021

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First of a kind SOLPS-ITER simulations on tokamak a configuration variable (TCV) that include nitrogen have been performed to model recent nitrogen seeded detachment experiments. Based on spectroscopic measurements, a nitrogen recycling coefficient R-p(N) ...

IOP PUBLISHING LTD2020

Reactions of nitrogen-containing compounds with ozone: kinetics and mechanisms

Sung Eun Lim

Nitrogen-containing moieties are widespread in natural waters in dissolved organic nitrogen and micropollu-tants. They are often susceptible to an electrophilic attack of ozone because of the electron-rich nature of the neutral form of nitrogen in organic ...

EPFL2020

C-C and C-N bonds are some of the most common structures in molecules ranging from drugs to catalysts and to food additives. Many coupling reactions were developed to form these types of bonds with excellent selectivity and good performance. Still, the syn ...

EPFL2020