Improved quantification of alite and belite in anhydrous Portland cements by Si-29 MAS NMR: Effects of paramagnetic ions
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Structure determination of materials is key to understanding their physical properties. While single-crystal X-ray diffraction is the gold standard for structures displaying long-range order, many materials of interest are polycrystalline and/or disordered ...
The properties of a physical system only exist in relation to its environment. This thesis presents the development of a novel spin qubit scanning probe microscope operating over a wide range of environmental conditions. The qubit, which sits at the heart ...
We report on the coexistence of magnetic order and disorder in the atomically disordered double perovskites Ca2FeRuO6 and CaSrFeRuO6. Powder x-ray and neutron diffraction were used to investigate the crystal structure and magnetic ordering of these oxides. ...
Nuclear magnetic resonance (NMR) methods are powerful tools employed in many fields, including physics, chemistry, material science, biology, and medicine. The use of NMR methodologies in an even wider range of applications is often hindered by the relativ ...
The research on layered van der Waals (vdW) magnets is rapidly progressing owing to exciting fundamental science and potential applications. In bulk crystal form, CrCl3 is a vdW antiferromagnet with in-plane ferromagnetic ordering below 17K, and CrI3 is a ...
The spin relaxation time in solids is determined by several competing energy scales and processes, and distinct methods are called for to analyze the various regimes. We present a stochastic model for the spin dynamics in solids which is equivalent to solv ...
Long-range magnetic ordering and short-range spin correlations in layered noncentrosymmetric orthogermanate Li2MnGeO4 were studied by means of polarized and unpolarized neutron scattering. The combined Rietveld refinement of synchrotron and neutron powder ...
Potassium chromium jarosite, KCr3(OH)(6)(SO4)(2) (Cr-jarosite), is considered a promising candidate to display spin liquid behavior due to the strong magnetic frustration imposed by the crystal structure. However, the ground state magnetic properties have ...
Solid-state NMR can provide information about the atomic level structure and dynamics of materials. It directly probes symmetry and structure at nuclear sites, and is especially useful for investigation of disordered or amorphous solids that lack long rang ...
Dynamic Nuclear Polarization (DNP) has recently emerged as a key method to increase the sensitivity of solid-state NMR spectroscopy under Magic Angle Spinning (MAS). While efficient binitroxide polarizing agents such as AMUPol have been developed for MAS D ...