First-principles study of the effect of nitrogen vacancies on the decomposition pattern in cubic Ti1-xAlxN1-y
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Thermodynamic modeling is a versatile tool for predicting the chemical composition cement during the hydration of cement. The quality of the thermodynamic modeling depends directly on the quality and completeness of thermodynamic database used. One of the ...
The enthalpies of formation of the intermetallic compounds in the Ge-Ni binary system have been determined by calorimetric measurement and first-principles calculations. Based on the results obtained and information available in the literature, the phase d ...
Calcium silicate hydrate (C-S-H) is the main hydrate phase in Portland cements. Its composition
varies depending on the Ca/Si ratio and on the presence of other ions such as aluminium (called CA-
S-H) or alkalis.
This thesis aimed to study the compositi ...
Phase equilibria in the CaO-Al2O3-Fe2O3-SO3 system have been studied, mainly at 1325 degrees C. In particular the solid solution compositions of ye'elimite Ca-4(Al6O12)SO4 and brownmillerite (C-2(A,F)) phases have been analysed and used to estimate the com ...
Slurries are widely used in important chemical and pharmaceutical manufacturing processes. In this presentation we report chemical monitoring and modeling of batch slurry reactions using optical and calorimetric measurement where key analytes are present i ...
We have used scanning micro x-ray diffraction to characterize different phases in superconducting KxFe2-ySe2 as a function of temperature, unveiling the thermal evolution across the superconducting transition temperature (T-c similar to 32 K), phase separa ...
The basic nature of alkali hydroxides (NaOH, KOH) when added to mixing water, increases the pH in proportion to the level of salt addition. For alite (impure tricalcium silicate; MIII-Ca3SiO5) hydration, this pH increase accelerates the rate of hydration a ...
We investigate how natural curvature affects the configuration of a thin elastic rod suspended under its own weight, as when a single strand of hair hangs under gravity. We combine precision desktop experiments, numerics, and theoretical analysis to explor ...
The modelling platform mu ic [1] has been used to investigate the mechanisms occurring during the hydration of alite. It is shown that it is possible to obtain a good simulation of the hydration kinetics through the implementation of two mechanisms: a diss ...
This research investigates the influence of alkali hydroxides on unrestrained volume changes. A detailed multi-method approach is used to characterize the progress of cement hydration, autogenous and drying volume changes (i.e., shrinkage), autogenous RH d ...