Broadband Dielectric Response in Hard and Soft PZT
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The properties of ferroelectric materials, such as lead zirconate titanate (PZT), are heavily influenced by the interaction of defects with domain walls. These defects are either intrinsic or are induced by the addition of dopants. We study here PbTiO3 (th ...
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Aging of piezoelectric properties was investigated in lead-free (1 - x)(Bi1/2Na1/2)TiO3-xBaTiO(3) doped with 1at.% Fe. The relaxor character of the un-poled material prevents macroscopic aging effects, while in the field-induced ferroelectric phase aging p ...
We reveal a strong elastic interaction between nonferroelastic domain walls in ferroelectric thin films. This interaction, having no analogue in bulk materials, is governed by elastic fields that are associated with the domain walls and extends to distance ...
This thesis consists of a theoretical analysis of charged domain walls in ferroelectrics based on Landau theory and the theory of semiconductors. First, the internal structure of a 180-degree charged domain wall is considered. It is shown that different re ...
A uniaxial compressive stress significantly modifies the dielectric and piezoelectric response of Pb(Zr,Ti)O3 (PZT)-based piezoceramics. In soft PZT, the pre-stress decreases both the piezoelectric coefficient and its increment with increasing dynamical st ...
Beyond the possibility of finding a lead-free piezoceramics as replacement for PZT, the world-wide research has focused on other mechanisms of electro-mechanical coupling alternative to piezoelectricity, such as electrostriction and, more recently, flexoel ...
The contribution of non-180 degrees domain wall displacement to the frequency dependence of the longitudinal piezoelectric coefficient has been determined experimentally in lead zirconate titanate using time-resolved, in situ neutron diffraction. Under sub ...