Microstructured reactors and supports for ionic liquids
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This thesis deals with the combined utilisation of a reaction calorimeter, the RC1® commercialised by Mettler Toledo and equipped with a 2 L glass reactor, and the heat transfer dynamics modelling of industrial reactors. By doing so, the temperature evolut ...
The aim of this work is to develop a microstructured reactor based on filamentous catalysts for the Oxidative Steam-Reforming of Methanol (OSRM), to produce hydrogen as feed for a fuel cell, in an autothermal way. Hydrogen is produced by the methanol Steam ...
This review highlights the synthesis of nitrogen-containing natural products via aza-annulation. Strategic, tactical, and methodological perspectives are discussed, including recent developments such as metal- or organocatalyzed reactions, oxidative or red ...
Two new modified hexacyclopeptides, aerucyclamides A and B, were isolated from the toxic freshwater cyanobacterium Microcystis aeruginosa PCC 7806. The constitution was assigned by spectroscopic methods, and the configuration determined by chemical degrada ...
Ionic liquids (IL) are the focus of growing interest over the last few years due to their low vapour pressure being beneficial for replacing common organic solvents with high vapour pressure. IL synthesised via alkylation are produced in batch or semi-batc ...
A review; an overview of recent developments from the Lab. of Organometallic and Medicinal Chem. at the EPFL in biphasic catalysis, involving aq. solns. and ionic liqs., and in CO2 redn. is presented. Progress in the use of ionic liqs., either by catalyst ...
Until about the year 2030, current-day nuclear power plants (NPPs) will be replaced by so-called Gen-III or Gen-III+ units, which are mainly based on light water reactor technology. The principal new features are increased safety and improved economical ef ...
The principal objective of this thesis is the development of a palladium catalyst supported on woven fabrics of activated carbon fibers (ACF) for the reactions of hydrogenations in liquid phase and the design of multiphase reactors using the characteristic ...
A series of 'dual-functionalised' ionic liquids, comprising imidazolium cations with various functionalities and the nitrile functionalised anion CH3H(BF3)CH2CN have been prepared; some exhibit very low viscosities-a highly valuable property in many a ...
