Optimal Process Design for Power Production from Wet Waste Biomass by Hydrothermal Gasification coupled to a Solid Oxide Fuel Cell

This report presents a system analysis of the production of electricity from wet waste biomass. A system of Hydrothermal Gasification is coupled with a Hybrid Cycle composed by a SOFC and two Gas Turbines, driven in an inverted Brayton--‐Joule cycle. A thermodynamic optimization approach, based on the system energy integration, is used to analyze several configuration options. The influence of the process design on performances is discussed for the most representative scenario that highlights the key aspects of the system. Optimization results prove that a systematic system design may reaches efficiencies higher than 60%.

Integrated Solid Oxide Fuel Cell

Emanuele Facchinetti

Distributed power generation and cogeneration of heat and power is an attractive way toward a more rational conversion of fossil and bio fuels. Solid oxide fuel cell (SOFC) – gas turbine (GT) hybrid systems are emerging as the most promising candidates enabling the achievement of a cleaner and more efficient conversion of a large variety of resources across a broad power range covering from small to medium scale applications. This thesis introduces an innovative concept of SOFC-GT hybrid system that allows reaching efficiencies higher than the state of the art while enabling the carbon dioxide separation and avoiding fuel cell pressurisation technical issues. Several hybrid system design alternatives based on this concept are analysed through a thermodynamic optimisation approach combining process modelling, advanced process integration techniques and multi-objective optimisation. A number of optimal hybrid system configurations are determined for different design targets. The results consistently demonstrate the higher energy conversion performance and flexibility enabled with respect to the state of the art. The innovative concept analysis is extended to two applications for which SOFC-GT hybrid cycles are expected to provide the most significant impact toward sustainability: the small scale distributed generation and the conversion of renewable resources. A simplified version of the new hybrid system layout is especially developed for small scale distributed generation, typical of residential building applications (5-10 kWel). Experimental data are used to prove the technical feasibility of the system and to assess the performance potentially achievable with currently feasible technologies. The results of the analysis underline that energy conversion efficiencies higher than traditional centralised power generation can be achieved even at such a small scale. A systematic process integration and optimisation approach is used to assess the energy conversion performance of the original SOFC-GT hybrid cycle fuelled with hydrothermally gasified wet waste biomass. The analysis highlights the considerable potential of the integrated system that allows for converting wet waste biomass into electricity with First Law efficiency higher than 60% while simultaneously enabling the separation of the biogenic carbon dioxide.

EPFL2012

Thermo-economic Optimization of a Solid Oxide Fuel Cell, Gas Turbine Hybrid System

Nordahl Autissier, Daniel Favrat, François Maréchal, Francesca Palazzi, Jan Van Herle

Large scale power production benefits from the high efficiency of gas-steam combined cycles. In the lower power range, fuel cells are a good candidate to combine with gas turbines. Such systems can achieve efficiencies exceeding 60%. High temperature Solid Oxide Fuel Cells (SOFC) offer good opportunities for this coupling. In this paper, a systematic method to select a design according to user specifications is presented. The most attractive configurations of this technology coupling are identified using a thermo-economic multi-objective optimization approach. The SOFC model includes detailed computation of losses of the electrodes and thermal management. The system is integrated using pinch based methods. A thermo- economic approach is then used to compute the integrated system performances, size and cost. This allows to perform the optimization of the system with regard to two objectives: minimize the specific cost and maximize the efficiency. Optimization results prove the existence of designs with costs from 2400

/kW for a 44% efficiency to 6700

/kW for a 70% efficiency. Several design options are analysed regarding, among others, fuel processing, pressure ratio or turbine inlet temperature. The model of a pressurized SOFC-microGT hybrid cycle combines a state-of- the-art planar SOFC with a high speed micro gas turbine sustained by air bearings.

2007

ENERGY STORAGE: LIQUID CH4 AND CO2 NETWORK INTEGRATION

Charles-Thomas Stern

In this project, we will study the energy storage with liquid methane linked to a CO2 network that provides heat for district heating. The generated methane enters an hybrid cycle composed of a solid oxide fuel cell and turbines to generate electricity. The goal of this project is to determine the global eciency of the system but also to optimize it with the help of softwares like Belsim Vali and Osmose. In addition, we determine its cost. At the end, we compare the global system with an equivalent one without the CO2 network integration.

2014