Origin of electronic absorption spectra of MLCT-excited and one-electron reduced 2,2′-bipyridine and 1,10-phenanthroline complexes
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The environment is important for the exact course of a chemical reaction. As an example of the strong influence of the environment on the reaction, this work studies the isomerization reaction of the chromophore retinal in the binding pocket of the protein ...
Absorption, emission and fluorescence-excitation spectra are reported for Hg atoms and Hg2 mols. in Ar, Kr, Xe and N2 matrixes upon excitation by synchrotron radiation in the 260-90 nm range. The fluorescence emitted from all levels issued from the 6s6p co ...
Absorption spectra of silane in the region of the first overtone of the Si-H stretch vibration have been recorded in a seeded supersonic jet expansion by cavity ring-down spectroscopy as well as in a static gas cell at room temperature by photoacoustic spe ...
We report here a new method to obtain electronic spectra of biomolecular ions that are produced in the gas phase by electrospray and cooled to ~10K in a 22-pole ion trap, and we demonstrate this technique by applying it to protonated tryptophan and tyrosin ...
We present a systematic study of the time-integrated fluorescence of native bacteriorhodopsin, as a function of excitation wavelength across the visible absorption band. While the fluorescence max. is unaffected, the spectrum broadens on the high-energy si ...