Direct observation of a ferri-to-ferromagnetic transition in a fluoride-bridged 3d–4f molecular cluster
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Magnetization curves of two rectangular metalorganic coordination networks formed by the organic ligand TCNQ (7,7,8,8-tetracyanoquinodimethane) and two different (Mn and Ni) 3d transition metal atoms [M(3d)] show marked differences that are explained using ...
High-resolution powder x-ray diffraction and single-crystal neutron diffraction were used to investigate the crystal structure and magnetic ordering of the compound Pr1-xCax VO3 (0
This thesis presents combined experimental and theoretical investigations of nanoscale, surface-supported magnets based on rare earths (RE) to understand and control the magnetic properties down to the scale of single atoms. We present the effects of adato ...
Double perovskite oxides A(2)BB'O-6 combining 3d and 4d or 5d transition metal ions at the B and B' sites feature a variety of magnetic and magneto-electric properties. Targeting Ba2FeOsO6, we synthesized powder samples of nonstoichiometric Ba2Fe1.12Os0.88 ...
It was shown recently that the Fe magnetization reversal in the Fe/MnAs/GaAs(001) epitaxial system, attained by temperature control of the regular stripe pattern of the MnAs alpha- and beta-phases, can also be driven by an ultrashort optical laser pulse. I ...
Isotropic and anisotropic magnetic behavior of the frustrated spin-chain compound beta-TeVO4 is reported. Three magnetic transitions observed in zero magnetic field are tracked in fields applied along different crystallographic directions using magnetizati ...
In this thesis I study the synthesis and basic physical properties characterization on 3d, 4d and 5d transition metal compounds. Great success has been obtained in 3d transition metal compounds, in which the electric states are well localized due t ...
The syntheses, structures, and magnetic properties of four new complex salts, (PPN){Mn-III(salphen)(MeOH)[M-III(CN)(6)]} 7MeOH (Mn2M 7MeOH) (M = Fe, Ru, Os and Co; PPN+ = bis(triphenylphosphoranylidene)ammonium cation; H2salphen = N,N'-bis(salicyliden ...
A 1D, end-on azido- and phenoxo-bridged, coordination polymer, Cu-2(mu-NAPPR)(mu(1,1)-N-3)(2) (1), (NAPPR(2-) = 1,3-bis(naphthylideneimino) propane dianion), was synthesized and characterized. The 1D branched-chain is built of two types of slightly di ...
Competing Jahn-Teller distortions combined with geometrical frustration give rise to a rich phase diagram as a function of x(Cu) and temperature in the spinel system Ni1-xCuxCr2O4. The Jahn-Teller distortion of the end members acts in opposite ways, with a ...