Hydroxylamine decomposition in the presence of iron studied by calorimetry, online mid-IR and UV-vis spectroscopy
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The aim of this work is to develop a microstructured reactor based on filamentous catalysts for the Oxidative Steam-Reforming of Methanol (OSRM), to produce hydrogen as feed for a fuel cell, in an autothermal way. Hydrogen is produced by the methanol Steam ...
The catalytic filters of sintered metal fibers (SMF) coated by thin MFI-type zeolite (silicalite-1, ZSM-5) films have been synthesized and tested in the reactor with structured catalytic bed. The catalysts show multifunctional behavior, combining catalysis ...
Theor. anal. of the reactor performance under unsteady-state conditions was carried out. The reactions are described by two kinetic models, which involve the participation in catalytic reaction of two types of active sites. The kinetic model I assumes the ...
A comprehensive review. The kinetics of various types of chem. reactions and the influence of transport processes on the effective reaction velocity (macrokinetics) are described. A survey is given on methods to det. the kinetics of reactions. Criteria for ...
The use of filamentous catalysts for innovative design of chemical reactors with structured catalytic beds is discussed in detail. The fluid dynamics attained in such reactors avoid transport limitations (mixing or heat- and mass-transfer) and increase rea ...
This review commences with a survey of the general synthetic routes leading to aminophosphines containing the P-NH subgroup. Recent examples involving functionalised and chiral aminophosphines are included. The synthesis and structural properties of deprot ...
This paper is aimed at introducing the organometallic chemist to the fascinating area of organometallic pharmaceuticals. It commences by identifying the properties of organometallic (transition metal) compounds that lend themselves to medical applications. ...
The rapid and complete characterization of chemical reaction mechanisms is of the utmost importance in terms of chemical understanding, safety and efficiency. In this presentation a new small volume reaction calorimeter (25-45mL) is described. With this re ...
The photocatalyst for the use in the production of hydrogen from water or aqueous solutions of organic compounds by using light energy, comprises carbon, in addition to a semiconducting photocatalytic material. The photocatalytic apparatus for the producti ...
(The Hydrogen Solar Production Company Limited, UK).2002
A novel dismantlable monolithic-type electrochem. promoted catalytic reactor and "smart" sensor-catalytic reactor unit has been constructed and tested for hydrocarbon oxidn. and NO redn. by C2H4 in presence of O2. In this novel reactor, thin (.apprx.20-4 ...