Ag-44(SR)(30)(4-): a silver-thiolate superatom complex
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With the increasing cognition of the importance of organic molecules, they are widely applied in printing, biological and pharmacological fields, because of their special capabilities of harvesting solar light, scavenging free radicals, and chelating metal ...
The nature of the bonding in ethylene and h2-P4 complexes, M(C2H4)2+ and M(h2-P4)2+, of group 11 metal cations (M = Cu, Ag, Au) has been explored by d. functional calcns. On the basis of the evaluation of symmetry orbitals, the contributions from the inter ...
We report inelastic neutron-scattering measurements of crystal-field transitions in PrFeAsO, PrFeAsO0.87F0.13, and NdFeAsO0.85F0.15. Doping with fluorine produces additional crystal-field excitations, providing evidence that there are two distinct charge e ...
[Rh-4 (CO)(6) (mu-Me2PCH2PMe2)(3)], the first example of a hexasubstituted derivative of Rh-4(CO)(12), has a ground state geometry in the solid state and in solution of C-s symmetry with four edge-bridging carbonyls and with each diphosphine ligand bridgin ...
Solvation dynamics, the process of solvent reorganization upon electronic excitation of a solute, is central to our understanding chemical reactions in liquid phase. Ultrafast optical studies of solvation dynamics have so far been carried out on polyatomic ...
We report on real-time detection of single electrons inside a n-p-n bipolar junction transistor at room temperature. Single electrons injected through the base-emitter junction trigger with a high probability the avalanche breakdown of the strongly reverse ...
Single-electron bipolar avalanche transistors (SEBATs) enable current sensing by electron counting at room temperature. Here, differential SEBAT circuits combining the functions of amplification and analog-to-digital (A/D) conversion are proposed and chara ...
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The interactions and structural formation of polyelectrolytes in solution and environmental stimuli-responsive water-soluble polymers are subjects of intense academic research, development, and application. An increasing number of novel materials are being ...
The photoexcitation and photoionization dynamics of sodium atoms deposited on the surface of helium nanodroplets and aromatic molecules (aniline, phenol and toluene) embedded in the interior of droplets have been investigated by a variety of spectroscopic ...
The excited state dynamics of silver atoms embedded in helium nanodroplets have been investigated by a variety of spectroscopic techniques. The experiments reveal that 5p 2P1/2 ← 5s 2S1/2 excitation of embedded silver atoms results almost exclusively in th ...