Oxygen and hydrogen peroxide reduction by 1,2-diferrocenylethane at a liquid/liquid interface
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This work contributes to the generalization of the Non-faradaic Electrochemical Modification of Catalytic Activity effect, known under the acronym NEMCA. This effect is observed for the first time over an oxide catalyst, namely IrO2 supported on yttria-sta ...
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Oxygen is a key substrate in animal cell metab. and its consumption is thus a parameter of great interest for bioprocess monitoring and control. A system for measuring it based on an oxygen balance on the liq. phase was developed. The use of a gas-permeabl ...
Oxygen and hydrogen peroxide electroredn. on La0.6Ca0.4CoO3 perovskite electrodes was studied in alk. media. Rotating disk electrodes were built using pure powders of the oxide to avoid any side reactions on the catalyst support, e.g. carbon. For O2 redn., ...
Hetero Diels-Alder reaction of oxadienes with 3,4-epoxy-2-methyleneoxolanes gave the corresponding 3,4-epoxy-1,6-dioxaspiro[4,5]-dec-7-enes with high stereoselectivity. Good yields of adducts were obtained in the presence of mild Lewis acis, such as zinc o ...
