Arene ruthenium complexes with phosphinoferrocene amino acid conjugates: Synthesis, characterization and cytotoxicity
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An organometallic 4d transition metal complex [CpRhCl2]2, together with commercially available dyes, was used to construct indicator displacement assays (IDAs) for the detection of peptides, amino acids, and nucleotides. The combination of the CpRh compl ...
Synthetic boron-doped diamond (BDD) thin film electrodes were tested for the electrogeneration of silver(II). In nitric acid, the kinetics of the silver(I)/silver(II) couple were studied by cyclic voltammetry. The results demonstrate that silver(II) can be ...
Cyclic voltammetry for the ferri-ferrocyanide redox couple was used to study the Ti/SnO2-Sb2O5 electrode prepd. by spray-pyrolysis under different conditions. Increasing the prepn. temp. and the duration of coating deposition results in a decrease of ip an ...
The electrochem. oxidn. of benzoic acid (BA) was studied on boron-doped diamond electrodes on acid medium by cyclic voltammetry and bulk electrolysis. In the potential region where the supporting electrolyte is stable, reactions occur, resulting in the los ...
The anodic methoxylation of formaldehyde dimethylacetal (FADMA) to trimethylorthoformate (TMOF) in basic methanol was investigated on boron-doped diamond (BDD) electrodes. Cyclic voltammetry and preparative electrolysis have shown that FADMA is electrochem ...
The synthesis of the trinuclear cluster cation H3RU3(C6H6)(C6Me6)(2)(O) (1) has been considerably improved by changes in the NaBH4 addition step and by introducing chromatographic methods; in addition, the redox and ligand exchange properties of 1 hav ...
The transfer mechanism of 1-pyrene sulfonate anion (PSA−) across the polarized water 1,2-dichloroethane (DCE) interface was investigated by a combination of electrochemical techniques and potential modulated fluorescence (PMF) spectroscopy under total inte ...
The service life of SnO2-Sb2O5 coated anodes prepd. by the spray pyrolysis technique using Ti or Ti/IrO2 substrate, was studied under galvanostatic conditions (100 mA cm-2 in 1M H2SO4 at 25 Deg). The presence of an IrO2 interlayer between the Ti substrate ...
The electrochem. oxidn. of phenol at synthetic boron-doped diamond thin film electrode (BDD) was studied in acid media by cyclic voltammetry, chronoamperometry, and bulk electrolysis. In the potential region of water stability (E
B-doped diamond films were deposited by large-area hot filament chem. vapor deposition (HFCVD) on Si and different industrial electrode materials, such as Ti, Zr, Nb, Ta, W, and graphite, with areas up to 50 * 60 cm2. B-doping levels ranging from 50 to sev ...
