Publication

The Transient Photocurrent and Photovoltage Behavior of a Hematite Photoanode under Working Conditions and the Influence of Surface Treatments

Publications associées (67)

A Material Approach to Dye-Sensitized Solar Cells

With growing concerns on future energy supplies, solar energy appears as an energy source whose potential remains to be tapped at a large scale. In the last two decades, dye-sensitized solar cells (DSCs) have been considered as a competitive means to conve ...

EPFL2014

Back Electron-Hole Recombination in Hematite Photoanodes for Water Splitting

Michael Graetzel, Florian Le Formal, Stanley David Tilley, Maurin Cornuz

The kinetic competition between electron-hole recombination and water oxidation is a key consideration for the development of efficient photoanodes for solar driven water splitting. In this study, we employed three complementary techniques, transient absor ...

American Chemical Society2014

Calculation of the Energy Band Diagram of a Photoelectrochemical Water Splitting Cell

Michael Graetzel, Stanley David Tilley, Matthias Schmid

A physical model is presented for the semiconductor electrode of a photoelectrochemical cell. The model accounts for the potential drop in the Helmholtz layer and thus enables description of both band edge pinning and unpinning. The model is based on the c ...

American Chemical Society2014

Hematite photoelectrodes for water splitting: evaluation of the role of film thickness by impedance spectroscopy

Kevin Sivula, Florian Le Formal

The electrochemical behavior of alpha-Fe2O3 photoelectrodes prepared by spray pyrolysis with different thicknesses was examined under dark and illumination conditions. The main charge transport phenomena occurring in the PEC cell photoelectrodes were chara ...

Royal Soc Chemistry2014

On the Texturing and Nanostructuring of Iron Oxide Photoanodes for Solar Water Splitting

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The world needs to think about the after fossil fuel era and while the sun baths the earth with a tremendous amount of energy, man must learn how to harvest and store it in order to dispose of a continuous supply meeting his needs. Water photo-electrolysis ...

EPFL2013

Metal Oxide Photoelectrodes for Solar Fuel Production, Surface Traps, and Catalysis

Kevin Sivula

The photoelectrochemical reduction of water or CO2 is a promising route to sustainable solar fuels but hinges on the identification of a stable photoanode for water oxidation. Semiconductor oxides like Fe2O3 and BiVO4 have been gaining significant attentio ...

Amer Chemical Soc2013

Cu-based p-type Oxide Photocathodes for Solar Hydrogen Production

Adriana Paracchino

The actualization of a hydrogen economy requires cost-effective and environmentally benign solutions to hydrogen production. Chemical energy in the form of hydrogen is more interesting than electricity to satisfy our ever-increasing energy demand because i ...

EPFL2012

Solar Energy Stored as Hydrogen

Jérémie Minh-Châu Brillet

The tandem photoelectochemical (PEC) cell based on oxide semiconductors for water splitting offers a potentially inexpensive route for solar hydrogen generation. At the heart of the device, a nanostructured photoanode for water oxidation is connected in se ...

EPFL2012

Dynamics of photogenerated holes in surface modified alpha-Fe2O3 photoanodes for solar water splitting

Michael Graetzel, Kevin Sivula, Takashi Hisatomi

This paper addresses the origin of the decrease in the external electrical bias required for water photoelectrolysis with hematite photoanodes, observed following surface treatments of such electrodes. We consider two alternative surface modifications: a c ...

National Academy of Sciences2012

Linear and Time-Resolved THz Spectroscopy of Photonic and Charge Transporting Systems

Jan Cornelius Brauer

Photo-induced charge separation and charge transport are fundamental processes in many energy conversion techniques, where light is converted into chemical energy (PEC), into electrical energy (solar cells) or in the opposite sense if electrical energy is ...

EPFL2012

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