Lattice Boltzmann simulations of the permeability and capillary adsorption of cement model microstructures
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This dissertation originates from an investigation about the arising of the modern, German building expertise involving the use of concrete, which develops during the first three quarter of the 19th century against the backdrop of a general modernisation p ...
At the turn of the 19th century, the production and use of concrete were limited by the unavailability of raw materials to produce good cement in several places. From that time onwards, the progress of chemistry and a number of empirical discoveries opened ...
Cement hydrates and their chemically bound water content are sensitive to changes in relative humidity (RH) and temperature. This may cause specific solid volume changes affecting dimensional properties of hydrated cement paste such as shrinkage, swelling ...
H-1 nuclear magnetic resonance (NMR), supported by a measurement of the degree of hydration using X-ray diffraction, has been used to fully characterise the nano-scale porosity and composition of calcium-silicate-hydrate (C-S-H), the active component of ce ...
High-performance concrete is sensitive to early-age cracking, mainly due to its rapidly-developing autogenous shrinkage. Autogenous shrinkage and internal relative humidity (RH) decrease are direct consequences of the emptying of capillary pores due to cem ...
The setting of Roman cement is so rapid as to make the use of retardation essential in most practical mortars. This work reports an approach to retardation of Roman cement mortars by means of a pre-hydration process in which pre-determined amounts of water ...
Supplementary cementitious materials (SCM) are known to reduce or even stop expansion due to alkali silica reaction (ASR) in concretes with reactive aggregates. Studies indicate that the main reason for this is the decrease in alkalinity of the pore soluti ...
Supplementary cementitious materials (SCMs) are currently used to replace part of the clinker to reduce the environmental impact of cement and to favor the use of local materials. Two representative SCM have been used in this work: slag and fly ash. Each o ...
This paper investigates the decomposition of three clayey structures (kaolinite, illite and montmorillonite) when thermally treated at 600 degrees C and 800 degrees C and the effect of this treatment on their pozzolanic activity in cementitious materials. ...
Tricalcium aluminate (C3A) is one of the main constituents of Portland cement. Even though it represents less than 10% of the total composition, its strong reaction with water can lead to a rapid setting, called flash set. Gypsum is added to regulate this ...
