Efficient and Rapid Synthesis of Chlorido-Bridged Half-Sandwich Complexes of Ruthenium, Rhodium, and Iridium by Microwave Heating
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A new series of iridium(III) mixed ligand complexes TBA[Ir(ppy)2(CN)2] (1), TBA[Ir(ppy)2(NCS)2] (2), TBA[Ir(ppy)2(NCO)2] (3), and [Ir(ppy)2(acac) (4) (ppy = 2-phenylpyridine; acac ...
Carbamoyl phosphate (CP) has been implicated as an educt for the synthesis of the CO and CN ligands of the metal centre of [NiFe]-hydrogenases in Escherichia coli, since CP synthetase mutants (carAB) are unable to generate active hydrogenases due to a bloc ...
The reaction of [RuCl3(AsPh3)(2)(MeOH)] with the dimeric complexes (cod)RhCl, (ppy)RhCl (ppy = cyclometalated 2-phenylpyridine), (cymene)RuCl2 and CP*MCl2 (M = Rh, Ir) has been investigated. The structure of the resulting products was s ...
Highly reactive tris-carbene Co(I) complexes [(TIMENaryl)Co]Cl react with org. azides to yield monomeric Co(III) imido complexes (TIMENaryl)Co(NAr') (aryl = mes, xyl; Ar = -C6H4-CH3, -C6H4-OCH3). The cobalt-imido fragment in these complexes is elec ...
Chloro-(h6-arene) complexes of Ru(II) with N-sulfonyl-1,2-ethylenediamine ligands that have one or two styrene side chains were synthesized and characterized. The chloro ligand was substituted with a diphenylphosphinato ligand and the resulting organometal ...
