Between photocatalysis and photosynthesis: Synchrotron spectroscopy methods on molecules and materials for solar hydrogen generation
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The world needs to think about the after fossil fuel era and while the sun baths the earth with a tremendous amount of energy, man must learn how to harvest and store it in order to dispose of a continuous supply meeting his needs. Water photo-electrolysis ...
Charge transport in nanoparticle-based materials underlies many emerging energy-conversion technologies, yet assessing the impact of nanometre-scale structure on charge transport across micrometre-scale distances remains a challenge. Here we develop an app ...
The limited fossil fuel resources and the increasing levels of greenhouse gases in the atmosphere are the driving forces in the research of alternative ways of energy production and storage. The use of solar energy is expected to grow as our society claims ...
Solar hydrogen generation by water splitting in photoelectrochemical cells (PEC) is an appealing technology for a future hydrogen economy. Hematite is a prospective photoanode material in this respect because of its visible light conjugated band gap, its c ...
Photocatalytic water splitting has been studied extensively as a promising technology for scalable and cost-efficient hydrogen production using solar energy. Although overall water splitting has been achieved under visible light irradiation, significant pr ...
A sustainable route to store the energy provided by the Sun, is to directly convert sunlight into molecular hydrogen using a semiconductor performing water photolysis. Hematite (α-Fe2O3) is promising for this application due to its ample abundance, chemica ...
The actualization of a hydrogen economy requires cost-effective and environmentally benign solutions to hydrogen production. Chemical energy in the form of hydrogen is more interesting than electricity to satisfy our ever-increasing energy demand because i ...
CsI thin film photocathodes of 600 nm thickness deposited on polished Al surfaces by resistive evaporation technique were studied by angle-resolved X-ray photoelectron spectroscopy (ARXPS), before and after UV-irradiation under vacuum. It is shown that the ...
Electronic structure of single crystal UPd3, UGe2, and USb2 has been measured from hard X-ray photoelectron spectroscopy (HAXPES) with 7.6 keV photons at the European Synchrotron Radiation Facility (ESRF). Lower photon energy angle-resolved photoelectron s ...
Solar hydrogen production via watersplitting with hematite (Fe2O3) has been limited by poor light absorption and a small hole diffusion length. These drawbacks can be overcome by using a high-surface-area host to support a thin layer of hematite-allowing p ...