Temperature dependence of the pressure induced monoclinic distortion in the spin S=1/2 Shastry-Sutherland compound SrCu2(BO3)(2)
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The effect of pressure on the Diels-Alder reaction was examined in room temperature ionic liquids, followed by high-pressure FT-IR spectroscopy using pressures up to 150 MPa. Pressure enhances the kinetic sensitivity of the reaction. The kinetic effec ...
We present a newly-developed microwave probe for performing sensitive high-field/multi-frequency electron spin resonance (ESR) measurements under high hydrostatic pressures. The system consists of a BeCu-made pressure-resistant vessel, which accommodates t ...
Novel extended tetrahedral forms Of CO2 have been synthesized recently under high-pressure conditions. We perform ab initio density functional theory calculations to investigate whether doping with Si can extend the stability range of such tetrahedral form ...
High-pressure scanning tunneling microscopy was used to study the room-temperature adsorption of CO on a Pt(111) single-crystal surface in equilibrium with the gas phase. The coverage was found to vary continuously, and over the entire range from 10(-6)-76 ...
Measurement of key plasma jet properties, such as the Mach number, electron density and temperature, in a low pressure environment, were performed using double Langmuir probes and Mach probes. In particular, under-expanded jets are studied in detail by per ...
First-principles molecular dynamics simulations at constant pressure have been used to investigate the mechanisms of compression of liquid SiO2. Liquid SiO2 is found to become denser than quartz at a pressure of about 6 GPa, in agreement with extrapolation ...
Raman spectra of Y2O3 single crystal were recorded at room temperature in a diamond anvil cell up to a pressure of 22 GPa. Two phase transitions were detected at pressures of 12 and 19 GPa. The different phases were identified with the three structures exh ...
Using X-ray diffraction with synchrotron radiation, we have studied the pressure changes induced by laser heating on samples compressed in a diamond-anvil cell. The method has been to compare experimentally observed phase transitions of Mg2SiO4 and SiO2 po ...
Thermomechanical modeling of a sample assembly (sample plus pressure transmitting medium) in a laser-heated diamond-anvil cell (LHDAC) is presented. Finite elements numerical calculation afforded to obtain the temperature distribution and the induced therm ...
EXAFS spectroscopy experiments have been carried out on quartz-like alpha-GaAsO4 and alpha-AlAsO4 at high pressure and room temperature. It has been shown that these materials exhibit two structural phase transitions; the first transition to a high pressur ...