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The combination of calcined kaolinitic clays and limestone in Limestone Calcined Clay Cement (LC3) is a promising approach to reduce the cost and the CO2 emissions of cement production by reducing the clinker content of cement. This thesis investigates the ...
This paper is the work of working group 3 of the RILEM Technical Committee on Hydration and Microstructure of Concrete with SCM (TC 238-SCM). The pore solution is an essential but often overlooked part of hydrated cements. The composition of the cement por ...
Cement hydrates and their chemically bound water content are sensitive to changes in relative humidity (RH) and temperature. This may cause specific solid volume changes affecting dimensional properties of hydrated cement paste such as shrinkage, swelling ...
Portlandite (Ca(OH)(2), CH) is the second most abundant hydrate formed in the reaction of Portland cement with water, making it an important component in the built environment. Formation of CH is closely linked to the growth of the main hydrate phase, calc ...
A novel clinker with low Ca/Si ratio and low sintering temperature was synthesized, and the property of the clinker was tested. A clinker sintered from industrial raw materials mainly contains rankinite (Ca3Si2O7), pseudowollastonite (Ca-3(Si3O9)) and ferr ...
Supplementary cementitious materials (SCMs) are currently used to replace part of the clinker to reduce the environmental impact of cement and to favor the use of local materials. Two representative SCM have been used in this work: slag and fly ash. Each o ...
This paper describes a novel approach to the quantitative investigation of the impact of varying relative humidity (RH) and temperature on the structure and thermodynamic properties of salts and crystalline cement hydrates in different hydration states (i. ...
Supplementary cementitious materials (SCM) lower the environmental impact of cement and concrete but react more slowly than Portland cement, which therefore limits the levels of substitution possible as reasonable early strengths are necessary. One of the ...
The main product of Portland cement hydration is C-S-H. Despite constituting more than half of the volume of hydrated pastes and having an important role in strength development, very little is known about the factors that determine its morphology. To inve ...
This paper reports on the mechanochemical activation by intensive grinding as an alternative way to produce pozzolanically reactive metakaolin. The physicochemical properties, pozzolanic reactivity and impact on cement hydration of mechanochemically and th ...