The existence of amorphous phase in Portland cements: Physical factors affecting Rietveld quantitative phase analysis
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Knowledge of the atomic-level structure is key to understanding and predicting properties of materials. X-ray diffraction (XRD) is the methods of choice for structures containing well-defined long-range order. However, many materials contain various degree ...
A novel clinker with low Ca/Si ratio and low sintering temperature was synthesized, and the property of the clinker was tested. A clinker sintered from industrial raw materials mainly contains rankinite (Ca3Si2O7), pseudowollastonite (Ca-3(Si3O9)) and ferr ...
Ye'elimite (Ca4Al6O12SO4 or C(4)A(3)S) is the main hydraulic mineral present in calcium sulphoaluminate cement (CSA). Its reaction is responsible for the (early) hydration and associated cement properties such as the chemical shrinkage. This paper discusse ...
Hardened cement paste in concrete wastes can be a valuable precursor material for the production of recycled cements. In the reported study, X-ray diffraction data of cementitious materials obtained by thermal processing of hardened pastes were quantitativ ...
In this paper, the replacement of high cost silica fume with calcined clay was investigated in UHPFRC mixes. The impact of two grades of calcined clay on the hydration and microstructural development of UHPFRC matrices was investigated, where 54% of the ce ...
X-ray powder diffraction (XRPD)-based quantitative phase analysis is a common technique for studying the hydration of cementitious systems. Hydrated cements often comprise several amorphous or nanocrystalline phases. This paper presents a protocol for the ...
Blended cements, where Portland cement clinker is partially replaced by supplementary cementitious materials (SCMs), provide the most feasible route for reducing carbon dioxide emissions associated with concrete production. However, lowering the clinker co ...
The replacement of clinker with supplementary cementitious materials (SCMs) is the most interesting solution to reduce the CO2 emissions from cement production. The abundant availability of clays, which have a sufficient amount of kaolinite content in Thai ...
Since the introduction of cementitious materials over 200 years ago, its use has multiplied many fold to be currently at 3 billion tonnes per year, accounting for about 8% of worldwide carbon emission which is forecast to double within the next 30 years. U ...
The combination of calcined kaolinitic clays and limestone in Limestone Calcined Clay Cement (LC3) is a promising approach to reduce the cost and the CO2 emissions of cement production by reducing the clinker content of cement. This thesis investigates the ...