On the Thermodynamics of Framework Breathing: A Free Energy Model for Gas Adsorption in MIL-53
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The mechanism of binding of the surfactant-cobalt(III) complex, cis-[Co(phen) 2(C 14H 29NH 2)Cl](ClO 4) 2{dot operator}3H 2O (phen = 1,10-phenanthroline, C 14H 29NH 2 = tetradecylamine) with bovine serum albumin (BSA) was investigated by UV-vis absorption, ...
Granular materials are large sets of macroscopic particles that interact solely via contact forces. The static behavior depends on the contact network and on the surface friction forces between grains; when they are set in motion (typically by vibrations) ...
We describe a low-temperature thermodynamic model for dynamic nuclear polarization (DNP) via continuous-wave partial saturation of electron spin resonance (ESR) lines that are both homogeneously and inhomogeneously broadened. It is a variant of a reasoning ...
The use of the interaction of two hydrides is a well-known concept used to increase the hydrogen equilibrium pressure of composite mixtures in comparison to that of pure systems. The thermodynamics and reaction kinetics of such hydride composites are revie ...
Phase equilibria in the Au-Ge-Ni ternary system were studied by means of scanning electron microscopy, electron probe microanalysis, X-ray diffraction, and differential scanning calorimetry. The phase relations in the solid state at 600 A degrees C as well ...
The thermodynamics of an electrically charged, multicomponent continuous medium with electromagnetic fields is analysed in the non-relativistic limit. Applying locally the first and second law of thermodynamics and Maxwell’s equations for a linear theory o ...
The temperature behavior of the generation of the second acoustic harmonics induced by an electric field during the transition of a crystal to the ferroelectric state has been considered based on the thermodynamic approach in the framework of the Landau mo ...
Numerical calculations of the evaporation kinetics of bulk volatile liquids and of water from smectite clay granules are compared with experimental results. The weight loss of the volatiles is analyzed by thermogravimetry and differential calorimetry. Unde ...
This work investigates sulfate attack in complex sulfate environments by exposing different binder types to various sulfate solutions and comparing predicted phase and volume changes with experimental data. The most important aspects of this work can be gr ...
The spatial organization of functional vegetation types in river basins is a major determinant of their runoff production, biodiversity, and ecosystem services. The optimization of different objective functions has been suggested to control the adaptive be ...