An Efficient Drug Metabolism Strategy Based on Microsome-Mesoporous Organosilica Nanoreactors
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One-step hydroxylation of benzene to phenol by N2O has been performed over structured catalytic beds made of ZSM-5 coatings on stainless steel grids. The catalysts demonstrated high activity with a selectivity toward phenol formation of 98%. A detailed kin ...
A new crosslinking scheme for producing polyethylene glycol hydrogels is described, involving a conjugate addn. reaction between PEG-multiacrylate and PEG-dithiol. Albumin was released from the gels with zero-order kinetics over four days. The gels are ame ...
Interaction of V2O5 with TiO2 during prepn. of V/Ti-oxide catalysts via solid-state reaction was studied using in situ FT-Raman spectroscopy, HRTEM and XPS. This interaction results in the formation of monomeric vanadia species with vanadium in tetrahedral ...
Target factor analysis (TFA) has been used successfully with reaction data to determine, without knowledge of reaction kinetics, the number of independent reactions and the corresponding stoichiometries. This paper analyzes the applicability of TFA techniq ...
A 33-residue de novo designed peptide ligase is reported which catalyzes the template-directed condensation of suitably activated short peptides with catalytic efficiencies in excess of 105 ([kcat/Km]/kuncat). The ligase peptide, derived from natural and d ...
A new method to investigate atmospheric chemical kinetics is presented. It is based on the pump and probe principle. Preliminary measurements are described on the decay rate of OH in the planetary boundary layer its concentration has been raised by laser f ...
The reaction rate, the catalyst potential, the catalyst work function and the voltammetric charge were in situ measured during a galvanostatic transient of ethylene combustion on an IrO2 catalyst at 380 Deg. The catalytic activity of an IrO2 catalyst could ...
In this paper the electrochem. promotion of RuO2 catalyst was studied for the oxidn. of C2H4 to CO2 and H2O. The reaction rate can be increased of up to a factor of 115 by anodic polarization. A kinetic model for the simulation of the open circuit reaction ...
The polycondensation of bis(ethylene glycol) terephthalate to poly(ethylene terephthalate) was investigated by thermogravimetric measurements at 260-300 Deg. A model is developed which enables to ext. the apparent kinetic parameters from the measured mass ...
The aim of the present work was to investigate whether uncoupling of catabolism from anabolism, which was often obsd. in heterotrophic microorganisms under energy-sufficient growth conditions, also occurs in the autotrophic bacterium M. thermoautotrophicum ...