Crystal structure diversity in the bis hydrotris-(3,5-dimethylpyrazolyl)borate iodouranium(III) complex: from neutral to cationic forms
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Here, we describe the synthesis of the single amino acid chelator DOTAlaP and four of its derivatives. The corresponding gadolinium(III) complexes were investigated for their kinetic inertness, relaxometric properties at a range of fields and temperatures, ...
Modeling proton-induced damage in biological systems, in particular in DNA building blocks, is of major concern in studies on cancer proton therapy. This is indeed an extremely complex process and analysis of the mechanism at the molecular level is of cruc ...
The reaction of the UO2+ precursor [(UO 2Py5)(KI2Py2)]n, with the potassium salt of the tetradentate aza β-diketiminate ligand L (L = 2-(4-tolyl)-1,3-bis(quinolyl)malondiiminate) affords the ...
One central aim of nanotechnology is the creation and exploitation of nanostructured materials with pre-programmed architecture and properties. The fabrication of functional nanostructures relies on versatile protocols of synthetic chemistry enabling the p ...
Hybrid DFT/classical molecular dynamics of the long-lived triplet excited state of [Ru(bpy)3]2+ (bpy=2,2-bipyridine) in aqueous solution is used to investigate the solvent-mediated electron localization and dynamics in the triplet metal-to-ligand charge-tr ...
The characterization of the interactions of Zn2+ ions with imidazole ligands is vital for understanding the function of a plethora of zinc enzymes at the molecular level. The infrared multiple photon dissociation (IRMPD) spectrum of mass selected Zn2+(imid ...
The title compound, (UO2)2Cl2(OH)2(H2O)4, was obtained unintentionally as the product of an attempted reaction between uranium(VI) oxide dihydrate, UO3⋅2H2O, and hydrogen bis(trifluoromethylsulfonyl)imide (HTf2N), in an experiment to obtain ...
The search for higher spatial resolution and better sensitivity stimulates the development of high-field (3 T) and ultrahigh field (>3 T) MRI scanners. Gadolinium-based MRI contrast agents, commercial ones used in clinics, as well as recently developed mor ...
[U(TpMe2)2I] exhibits at low temperatures single molecule magnet (SMM) behaviour comparable to its bipyridine derivative and related single ion U(iii) complexes recently reported as SMMs. The trend of variation of the energy barrier for the magnetic relaxa ...