Publication
Catalyst Development for Selective Hydrogenation of Functionalized Alkynes and Nitroarenes
Publications associées (107)
Impact of organic-ligand shell on catalytic performance of colloidal Pd nanoparticles for alkyne gas-phase hydrogenation
Lioubov Kiwi, Fernando Cardenas Lizana, Daniel André Samuel Lamey, Irina Prokopyeva
Monodispersed Pd nanoparticles (NPs) have been prepared by colloidal technique and deposited on a structured support consisting of carbon nanofibers (CNF) grown on sintered metal fibres (SMF). The surface properties of Pd NPs have been fine-tuned by (i) ch ...
Elsevier2014Size-Controlled Pd Nanoparticles in 2-Butyne-1,4-diol Hydrogenation: Support Effect and Kinetics Study
Lioubov Kiwi, Fernando Cardenas Lizana, Charline Berguerand
Structured catalyst has been developed for C–C triple bond three-phase hydrogenation. The sintered metal fiber (SMF) coated by different oxides served as support for monodispersed Pd nanoparticles (6.4 ± 0.5 nm). The effect of acid–base properties and redu ...
Amer Chemical Soc2014The use of Pd catalysts on carbon-based structured materials for the catalytic hydrogenation of bromates in different types of water
The aim of this work is to study the activity of new Pd catalysts, supported on two different nano structured carbon materials, for bromate catalytic hydrogenation. The influence of the support has been studied, obtaining the best results with a palladium ...
Elsevier2014Adsorption of Small Hydrocarbons on the Three-Fold PdGa Surfaces: The Road to Selective Hydrogenation
Harald Brune, Roland Widmer, Daniele Passerone, Jan Prinz
Intermetallic compounds are a promising class of materials as stable and selective heterogeneous catalysts. Here, the (111) and (-1-1-1) single crystal surfaces of the PdGa intermetallic compound were studied as model catalysts with regard to the selective ...
American Chemical Society2014Aqueous stabilisation of carbon-encapsulated superparamagnetic alpha-iron nanoparticles for biomedical applications
Heinrich Hofmann, Marie-Gabrielle Chantal Brigitte Ollivier Beuzelin, Lionel André Maurizi, Sandra Caroline Galmarini, Géraldine Sylvie Coullerez
Carbon-based nanomaterials, such as carbon-encapsulated magnetic nanoparticles (CEMNP, core@shell), show a wide range of desirable properties for applications in the biomedical field (clinical MRI, hyperthermia), for energy production and storage (hydrogen ...
Royal Society of Chemistry2014Olefin Hydrogenation with Single-Site Gold
Butene hydrogenation activity is intimately connected with the occupied and unoccupied electronic states of gold active site. We prepare well-defined Au(III) sites in IRMOF-3 structure, and tuned the metal density-of-states by replacing the substituent gro ...
Polish Academy of Sciences Warsaw2014Sn surface-enriched Pt–Sn bimetallic nanoparticles as a selective and stable catalyst for propane dehydrogenation
David Lyndon Emsley, Lidong Li
A new one pot, surfactant-free, synthetic route based on the surface organometallic chemistry (SOMC) concept has been developed for the synthesis of Sn surface-enriched Pt-Sn nanoparticles. Bu3SnH selectively reacts with [Pt]-H formed in situ at the surfac ...
Elsevier2014Ammonium formate decomposition over Au/TiO2: a unique case of preferential selectivity against NH3 oxidation
The unique selectivity of Au/TiO2 for converting ammonium formate to CO2 in the presence of excess O2 and H2O without oxidising NH3 up to 300 °C is reported. The catalyst is highly stable and selective even after severe hydrothermal aging. ...
Royal Soc Chemistry2014The development of gold catalysts for use in hydrogenation reactions
With increasing emphasis placed on cleaner chemical synthesis, energy efficiency and waste minimisation, the manufacture of pharmaceuticals and fine chemicals is undergoing a progressive shift from conventional stoichiometric organic processes to a harness ...
Springer2013Rational development of an electron-rich platinum nanocatalyst for the oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxilic acid under mild conditions
Paul Joseph Dyson, Zhaofu Fei, Ning Yan, Georgios Savoglidis, Sviatlana Siankevich
Valorization of lignocellulosic biomass for the production of commodity chemicals using various chemical methods continues to attract considerable attention. A wide and diverse range of different chemicals can be obtained from biomass and many different do ...
2013