Lanthanide coordination chemistry: from old concepts to coordination polymers
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The phenomenon of magnetism is one of the key components of today's technological progress. Magnetic interactions and magnetic materials are essential for the scientific disciplines of physics, chemistry and biology, making this subject truly multidiscipli ...
The heterobitopic ligands LAB4 and LAB5 have been designed and synthesised with the ultimate aim of self-assembling dual-function lanthanide complexes containing either a magnetic and a luminescent probe or two luminescent probes emitting at different wave ...
This thesis deals with the self-organization of individual building blocks, specifically organic molecules and metal atoms, into supramolecular structures on metal surfaces under ultra high vacuum conditions (UHV). Self-organization of supramolecular syste ...
Abstract: The heterobitopic ligands LABX (X=1,2, 3,4 or 5),diff ering only by a Cl or NEt2 substituent,have been designed to complex with a pair of lanthanide ions to form triple-stranded bimetallic helicates of overall composition [Ln2ACHTUNGTRENUNG(LABX) ...
A rational approach to the formation of pure heteropolymetallic lanthanide complexes that uses a two-step assembly strategy and exploits the different size requirements of the two metals included in the final structure is described. The investigation of th ...
This overview presents recent work on the coordination chemistry and catalytic activity of bis-phosphine ruthenium(II)-arene complexes, RuCl(PPh3)(PR3)(eta(6)-arene), carried out in the Laboratory of Organometallic and Medicinal Chemistry at the EPFL. ...
Reaction in water between rare earth ions (Ln ) Y, La-Tm, except Pm) and the sodium salt of terephthalic acid leads to a family of lanthanide-based coordination polymers of general formula [Ln2(C8H4O4)3(H2O)4]n with Ln ) La-Tm or Y. The isostructurality of ...
The hydrothermal synthesis and structural characterization of the lanthanide silicate system [Na6Ln2Si12O30x H2O] (Ln=La3+, Sm3+, Eu3+, Gd3+, and Tb3+), named AV-21, has been reported. Structural elucidation of the Sm3+ analogue (isomorphous with the Eu3+, ...
Hybrid solids, made of chem. dissimilar components, have drawn much interest in advanced materials synthesis due to their structural versatility and multifunctional properties. For example, metal-org. frameworks (MOFs) have been extensively explored for th ...
