Publication
It is known that excitation by visible light of the singlet metal-to-ligand charge-transfer (1MLCT) states of Fe(II) complexes leads to population of the lowest-lying high-spin quintet state (T-5) with unity quantum yield. Here we investigate this so-called spin crossover (SCO) transition in aqueous iron(II) tris(bipyridine). We use pump-probe transient absorption spectroscopy with a high time resolution of
Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Paul Varava, Wolfram Feuerstein
Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Davide Toniolo
Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Laura Piveteau, Bastiaan Kooij, Zhaowen Dong, Paul Varava