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The first part of this laboratory study deals with heterogeneous reactions of bromine- and chlorine-containing species relevant to the atmosphere with solid model alkali salt substrates. The second part of this work treats the heterogeneous interaction of ...
The solubility of hydrogen and the corresponding Henry coefficients for 11 ionic liquids have been determined in situ at 100 atm H-2 pressure and are much lower than expected; attempts to correlate the solubility of hydrogen in the ionic liquids with the r ...
The dissociation of methane on a nickel catalyst is a key step in steam reforming of natural gas for hydrogen production. Despite substantial effort in both experiment and theory, there is still no atomic-scale description of this important gas-surface rea ...
The aim of this thesis is twofold: on the one hand to demonstrate a new method of building magnetic nanostructures at surfaces and on the other hand to present the construction of a new 1K UHV Low Temperature STM aimed at coupling the spatial resolution of ...
Quinodimethanes are highly reactive toward dienophiles since Diels-Alder cycloaddn. results in an arom. product. D. functional-based 13C, 1H NMR, NICS, and MO-NICS calcns. indicate that the increase of arom. character of the developing benzenoid ring along ...
Metal nickel and copper grids are shown to be suitable supports for structured combustion catalysts. The increase of sp. surface area (SSA) of metal grids was achieved due to the porous outer layer with the structure of Raney metal developed on the wire su ...
We propose a new mechanism for the electroreduction of hydrogen in acidic media. The specific model and theoretical calculations are designed for the Pt(111) surface, because this is the only face that exhibits a clear first order phase transition. The bas ...
We used classical molecular mechanics (MM) simulations and quantum mechanical (QM) structural relaxations to examine the active site of myosin when bound to ATP. Two conformations of myosin have been determined by x-ray crystallography. In one, there is no ...
Cross-correlated relaxation of multiple-quantum coherences in NMR was used to investigate hydrogen bonds in Watson-Crick base pairs, based on the interference between various relaxation mechanisms. [on SciFinder (R)] ...
Structured palladium catalysts suitable for three-phase reactions have been developed based on woven fabrics of active carbon fibers (ACF) as the catalytic supports. The Pd/ACF were tested in liq.-phase hydrogenation of 2-butyne-1,4-diol showing a selectiv ...