Probing wavepacket dynamics using ultrafast x-ray spectroscopy
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The photocycle of rhenium carbonyl complexes, type facial-[Re(L)(CO)3(diimine)]n [L=halide / n=0, L=4-Ethyl-pyridine (Etpy)- Imidazole (ImH) /n=+1, diimine= bpy , 10- phenanthroline (phen), 4,4'-dimethyl-2,2'-bpy (dmb)] was studied using a set of ultrafast ...
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We present a review of wave packet dynamics in different systems and stress their relation to information on the ultrafast structural changes. We show how dynamical information is obtained from ultrafast optical pump-probe studies on structural changes in ...
We demonstrate for the first time (to our knowledge) characterization of ultrashort IR pulses by self-referenced spectral interferometry. Both sub-55-fs pulses from 1.4 mu m to 2 mu m and broadband 2.5-cycle pulses at 1.65 mu m (13 fs FWHM) are characteriz ...
In this thesis we followed the synergetic approach of combining ultrafast optical and X-ray spectroscopies to unravel the electronic and geometric structural dynamics of the solvated binuclear transition metal complex [Pt2(P2O5H2)4] 4- (PtPOP). This molecu ...
Ultrafast X-ray absorption spectroscopy is a powerful tool to observe electronic and geometric structures of short-lived reaction intermediates. The ab initio FEFF9 code is applied to simulate the Pt L-3-edge XANES spectrum of the photocatalytic diplatinum ...
Electronic structure changes are at the origin of the making, breaking and transformation of bonds. These changes can be visualized by measuring the geometric structure in "real-time" during the course of a chemical reaction, a biological function or a phy ...
