Investigation of a Pt containing washcoat on SiC foam for hydrogen combustion applications
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Molybdenum disulfide microparticles in suspension in an aqueous acidic solution adsorb at the interface with an organic electrolyte solution containing the reducing agent, decamethylferrocene, to catalyse hydrogen evolution. This catalytic process has been ...
The catalytic action of Mo2N and Au/Mo2N has been assessed in the selective gas phase hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroaniline (p-CAN). The nitrides were synthesised via temperature programmed treatment of MoO3 in H-2 + N-2 and Au i ...
The nickel(II) hydride complex [(MeN2N)Ni-H] (2) was synthesized by the reaction of [(MeN2N)Ni-OMe] (6) with Ph2SiH2 and was characterized by NMR and IR spectroscopy as well as X-ray crystallography. 2 was unstable in solution, and it decomposed via two re ...
Optimized synthesis of Ti-precursor 'titanylnitrate' for one step combustion synthesis of N- and C-doped TiO2 catalysts were reported and characterized by using powder X-ray diffraction (XRD), transmission electron microscopy (TEM), diffused reflectance UV ...
In recent years, a strong emphasis in research towards creating sustainable and environmental friendly chemical processes has propelled the development of novel types of catalytic systems that combine advantages from homogeneous and heterogeneous processes ...
Poly(vinylpyrrolidone) (PVP)-stabilized Pd nanocubes were synthesized, deposited on a carbon-based support, and subsequently treated with UV-ozone (UVO) in order to eliminate the traces of PVP still present on the surface. Cubes, being a thermodynamically ...
The catalytic gas phase hydrogenation of m-dinitrobenzene (1 atm, 423 K) over laboratory synthesised (1 mol%) Au supported on Al2O3, TiO2, Fe2O3 and CeO2 and a reference Au/TiO2 (World Gold Council) has been investigated. The catalysts were prepared by dep ...
In the present work, CeO2 nanopowder was synthesized via a reverse precipitation method using CeCl3 center dot 7H(2)O, NH4OH and sodium dodecyl sulfate as raw materials. The effect of thermal treatment on the crystal growth, surface area and chemical bonds ...
Metal borohydrides are potential materials for solid-state hydrogen due to their high gravimetric and volumetric hydrogen densities. Among them, Ca(BH4)2 is particularly interesting because of the predicted suitable thermodynamic properties. In this work, ...