Bacterial inactivation with iron citrate complex: A new source of dissolved iron in solar photo-Fenton process at near-neutral and alkaline pH
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Novel photo-Fenton catalysts were prepared by immobilizing iron species on commercial bentonite plates via two methods: (1) ion exchange reaction (Fe3+ vs. Na+) by aqueous suspension powder-clay/FeCl3 followed by plate preparation, and (2) forced hydrolysi ...
Enhanced in situ bioremediation of chlorinated solvents is, especially in source zone remediation, often limited through the accompanied high acidification of groundwater. This acid built-up originating from the dechlorination itself and fermentation produ ...
A Pd-based indicator displacement assay for the fluorimetric sensing of carbohydrates has been developed. The assay allows the detection of saccharides in the low millimolar concentration range in water at neutral pH. ...
A tripodal ligand based on the 8-hydroxyquinolinate binding unit yields a soluble and highly stable bis-hydrated Gd3+ complex in water (pGd = 19.2(3)) with relaxivity change in the pH range 4.5-7.4 and Nd3+, Yb3+ analogues with sizeable NIR emission upon e ...
Mechanical, physical and manufacturing properties of cast iron make it attractive for many fields of application, such as cranks and cylinder holds. As in design of all metals, fatigue life prediction is an intrinsic part of the design process of structura ...
The preparation of iron oxide-coated polymer films and their photocatalytic activity in organic pollutants degradation and bacterial inactivation is described. Polyvinyl fluoride (PVF), polyethylene (PE) and polyethylene terephtalate (PET) films were used ...
Photocatalytic degradation of phenol, nalidixic acid, mixture of pesticides, and another of emerging contaminants in water was mediated by TiO2 and iron oxide immobilized on functionalized polyvinyl fluoride films (PVFf-TiO2-Fe oxide) in a compound parabol ...
The photodegradation of phenol and dichloroacetic acid (DCAA) by \ce{BiVO4} was studied in the absence as well as presence of selected electron scavengers. The experiments were performed under the visible (vis) irradiation of aqueous solutions over a wide ...
The synthesis, structure, and reactivity of a five-coordinate model complex of [Fe]-hydrogenase are described. The work suggests that the iron center in [Fe]-hydrogenases could be five-coordinate in the resting state. ...
Background Two porphyry copper mines located in southern Peru initiated the discharge of mine wastes (tailings) for a final shore deposition in the Bay of Ite (Pacific Ocean). 780 millions metric tons of tailings were deposited, which formed a delta with a ...