Spindle-shaped nanoscale yolk/shell magnetic stirring bars for heterogeneous catalysis in macro- and microscopic systems
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Catalytic processes and in particular heterogeneous catalysis are vital for todays industry. However, many industrial catalytic processes require high temperatures and pressures to work efficiently. This stands in contrast to biological catalysts, which fu ...
Oxidation catalysis on reducible oxide-supported small metal clusters often involves lattice oxygen. The present work aims at differentiating whether the reaction takes place at the cluster/support interface or on the cluster. To that purpose, we trace the ...
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The chemical and physical properties of nanoclusters largely depend on their sizes and shapes. This is partly due to finite size effects influencing the local electronic structure of the nanocluster atoms which are located on the nanofacets and on their ed ...
Metal organic supramolecular chemistry on surfaces has matured to a point where its underlying growth mechanisms are well understood and structures of defined coordination environments of metal atoms can be synthesized in a controlled and reproducible proc ...
Intermetallic compounds are a promising class of materials as stable and selective heterogeneous catalysts. Here, the (111) and (-1-1-1) single crystal surfaces of the PdGa intermetallic compound were studied as model catalysts with regard to the selective ...
