Homonuclear decoupling for spectral simplification of carbon-13 enriched molecules in solution-state NMR enhanced by dissolution DNP
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Major breakthroughs have recently been reported that can help overcome two inherent drawbacks of NMR: the lack of sensitivity and the limited memory of longitudinal magnetization. Dynamic nuclear polarization (DNP) couples nuclear spins to the large reserv ...
Nuclear magnetic relaxation in the presence of paramagnetic centres has gained increasing interest in recent years partly due to its importance for contrast agents in magnetic resonance imaging. Rational design of new more efficient agents is possible as a ...
In magic angle spinning solid-state NMR, the homonuclear J-couplings between pairs of spin-1/2 nuclei may be determined by studying the modulation of the spin echo induced by a pi-pulse, as a function of the echo duration. We present the theory of J-induce ...
Coherence transfer from ‘spy nuclei’ such as 1H or 13C (S = 1/2) was used to excite single- or double-quantum coherences of 14N nuclei (I = 1) while the S spins were aligned along the static field, in the manner of heteronuclear single-quantum correlation ...
A method is described to det. long-range cross-correlations between the modulations of an anisotropic chem. shift (e.g., of a C' carbonyl carbon in a protein) and the fluctuations of a weak long-range dipolar interaction (e.g., in cross-correlation between ...
The performance of deuterium-carbon correlation (DECOR) spectroscopy for the assignment and measurement of deuterium quadrupolar couplings in fully deuterated liquid crystalline phases is analyzed. The experiment relies on a broadband polarization transfer ...
An approach for enhancing the NMR sensitivity of the central transition of spin-3/2 nuclei is presented. Through selective excitation of the satellite transitions using a fast 180 degrees phase alternating pulse train during magic-angle spinning a selectiv ...
Numerical simulations and experiments are used to show that the spin dynamics of the dipolar-coupled networks in solids is often strongly dependent on crystallite orientation. In particular, different rates of dephasing of the magnetisation mean that NMR s ...
We report on NMR evidence about a novel effect in La1-xCa xMnO3+δ systems with cation deficience. We show that in the low-Ca-doping regime, these systems exhibit a very strong hyperfine field at certain La nuclear sites, which is not present in the stoichi ...
In systems with dipolar relaxation in isotropic phase, it is possible to measure the extent of cross correlation of the fluctuations of two selected dipole-dipole interactions A-M and A-X by selectively exciting and spin-locking the transverse magnetizatio ...
