Piezoelectric response of BiFeO3 ceramics at elevated temperatures
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Ferroelectric oxides, such as lead zirconate titanate, have proved invaluable due to their excellent dielectric and piezoelectric properties. These classes of materials possess a large electric polarization below the Curie temperature. Regions of the cryst ...
Bismuth ferrite (BiFeO3) is difficult to pole because of the combination of its high coercive field and high electrical conductivity. This problem is particularly pronounced in thick films. The poling, however, must be performed to achieve a large macrosco ...
Since the discovery of a high piezoelectric response in AlScN by Akiyama and coworkers in 2009, a number of works of other groups confirmed the large increase of piezoelectricity when partially substituting Al cations by Sc cations, as long as the alloy gr ...
Despite the technological importance of hard and soft PZT, Pb(Zr,Ti)O3, ceramics, the mechanisms of ferroelectric hardening and softening remain widely discussed in the literature. The hardening and softening phenomena have traditionally been investigated ...
[001]-Oriented barium titanate (BaTiO3) ceramics were prepared by templated grain growth using [001]-oriented plate-like template BaTiO3 particles, synthesized via the molten salt method. Platelets synthesized in a 2-step or 3-step molten salt were used in ...
Springer Verlag2015
This work was originally motivated by the search for high-temperature piezoceramic materials with low acoustic impedance and high electromechanical coupling. The temperature and pressure behavior of two PZT-based materials with engineered porosity, Pz31 & ...
The interfaces in complex oxides present unique properties exploitable in nanoscale devices. Recent studies on ferroelectric BiFeO3, BaTiO3, and Pb(Zr, Ti) O-3 have revealed an unusually high electric conductivity of the domain walls (DWs), adding another ...
The contribution of non-180 degrees domain wall displacement to the frequency dependence of the longitudinal piezoelectric coefficient has been determined experimentally in lead zirconate titanate using time-resolved, in situ neutron diffraction. Under sub ...
Enhancement of ferroelectric properties, both spontaneous polarization and Curie temperature under negative pressure had been predicted in the past from first principles and recently confirmed experimentally. In contrast, piezoelectric properties are expec ...
Beyond the possibility of finding a lead-free piezoceramics as replacement for PZT, the world-wide research has focused on other mechanisms of electro-mechanical coupling alternative to piezoelectricity, such as electrostriction and, more recently, flexoel ...