Ultra-sensitive Infrared Spectroscopy of Proteins with Collective Excitations of Nanoplasmonic Arrays
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Metallic nanostructures show interesting optical properties due to their plasmonic resonances, and when arranged in three-dimensional (3D) arrays hold promise for optical metamaterials with negative refractive index. Towards this goal a simple, cheap, and ...
Infrared absorption spectroscopy is a powerful biochemical analysis tool as it extracts detailed molecular structural information in a label-free fashion. Its molecular specificity renders the technique sensitive to the subtle conformational changes exhibi ...
We present an approach for rational design and optimization of plasmonic arrays for ultrasensitive surface enhanced infrared absorption (SEIRA) spectroscopy of specific protein analytes. Motivated by our previous work that demonstrated sub-attomole detecti ...
High-resolution infrared absorption spectroscopy of acetylene gas is demonstrated in a dispersion-engineered photonic crystal waveguide under slow-light propagation. Experimental enhancement factors of 0.31 and 1.00 are obtained for TE and TM polarization, ...
In industry, spectroscopy is used to monitor batch chemical reactions and to maximize production of a material for a minimum cost. However, there are many challenges involved in using spectroscopic methods to characterize reaction systems that undergo crys ...
High-resolution infrared absorption spectroscopy of acetylene gas is demonstrated in dispersion-engineered photonic crystal waveguides under slow light propagation. Individual absorption profiles are obtained for both TE and TM polarizations for group indi ...
Society of Photo-Optical Instrumentation Engineers (SPIE)2012
Dimethylaminonitrene complexes of IMesM+ (IMes = 1,3-bis(2,4,6-trimethylphenyl)- imidazol-2-ylidene; M = Cu, Ag, Au) were prepared in the gas phase and structurally characterized by high-resolution infrared spectroscopy of the cold species, ion-molecule re ...
We calculate the transverse and the longitudinal infrared absorption spectra of the hydrated silicon surface using a first-principles approach. The absorption spectra are computed for two different configurations of water molecules dissociatively chemisorb ...
We report the design and characterization of a new molecular-beam/surface-science apparatus for quantum state-resolved studies of gas/surface reaction dynamics combining optical state-specific reactant preparation in a molecular beam by rapid adiabatic pas ...
We demonstrate a novel fabrication approach for high-throughput fabrication of engineered infrared plasmonic nanorod antenna arrays with Nanostencil Lithography (NSL). NSL technique, relying on deposition of materials through a shadow mask, offers the flex ...