Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands
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The reactions of [Fe2(CO)9] with 2-exo,3-exo-bis(chloromethyl)-5,6-di(methylidene)-7-oxabicyclo[2.2.1]hep tane (5) and with 5,6-di(methylidene)-7-oxabicyclo[2.2.1]heptane-2-exo,3-exo-dimethyl bis(methanesulfonate) (6) afforded, together with the correspond ...
Polarized fluorescence spectra were recorded in the vicinity of the Se and Br K edges on crystals of the selenated protein aldose reductase in complex with a brominated inhibitor molecule. The X-ray absorption, refraction and resonant scattering tensors as ...
A series of imidazolium dicarboxylic acids have been prepd. from the reaction of the 1,3-bis(carboxymethyl)imidazolium zwitterion with the Bronsted acids HX (X = F, Br, Cl, ClO4). The structures of these acids have been established in the solid ...
Hexafluoro-2-butyne, CF(3)Cequivalent toCCF(3), reacts with the triangulo-clusters [Pt-3 (mu-CO)(3)(PR3)(3)] to give the diplatinum(o) compounds [Pt-2(CO)(2)(PR3)(2)(mu-eta(2):eta(2)-CF(3)Cequivalent toCCF(3))] {PR3=PPh3 (1), PBzPh(2) (2), PCy3 (3), (PPr3) ...
By checking the chemistry underlying the concept of "supramolecular cluster catalysis" we identified two major errors in our publications related to this topic, which are essentially due to contamination problems. (1) The conversion of the "closed" cluster ...