Flexible metal organic framework compound, Ni(1,2- bis(4-pyridyl)ethylene)[Ni(CN)4]n, for CO2 sorption applications
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Zeolites are one class of porous materials that are currently being explored for sepn. applications in the aim of reducing environmentally harmful carbon dioxide (CO2) from the combustion of fossil fuels. The several archetypical zeolites being employed or ...
Copper and silver cation-exchanged zeolite SSZ-13 present an interesting opportunity to study the mechanism of interaction of adsorbate gases, primarily hydrogen (H2), with the ion-exchange sites in zeolites as there is only one type of cation site, in con ...
The comparable order of magnitude between interatomic distances in a crystal and the wavelength of X-rays make X-ray crystallography the ideal analytical tool to gain insight into the structure of crystalline material, including biomolecules. Nevertheless, ...
The purpose of the research was to find a simple synthesis with high nuclearity cluster-based compds. The two compds. that the research research was focused on are Cs5V14O42As8Cl (V14Cl) and Cs11Na3V15O36Cl6 (V15Cl). V14Cl and V15Cl were prepd. in a nitrog ...
A tetragonal molybdenum nitride (β-Mo2N) has been prepared by temperature programmed treatment of MoO3 in flowing N2 + H2 and for the first time shown to catalyze the liquid phase selective hydrogenation (T = 423 K; PH2=11bar) of a series of para-substitut ...
The catalytic action of Mo2N and Au/Mo2N has been assessed in the selective gas phase hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroaniline (p-CAN). The nitrides were synthesised via temperature programmed treatment of MoO3 in H-2 + N-2 and Au i ...
A tetragonal molybdenum nitride (beta-Mo2N) has been prepared by temperature programmed treatment of MoO3 in flowing N-2 + H-2 and for the first time shown to catalyze the liquid phase selective hydrogenation (T = 423 K; P-H2 = 11 bar) of a series of para- ...
Neutron diffraction is a technique often used for the non-destructive characterization of residual stresses in engineering materials and components. Measuring stresses within partially hollow objects with complex internal geometry however is challenging du ...
This study was conducted to synthesize thermally-robust metal-org. frameworks with high internal surface areas and a high concn. of open metal coordination sites for hydrogen storage. A no. of strategies were used for generating open metal coordination sit ...
The hydrogen storage properties of Fe2(dobdc) (dobdc4- = 2,5-dioxido-1,4-benzenedicarboxylate) and an oxidized analog, Fe2(O2)(dobdc), have been examd. using several complementary techniques, including low-pressure gas adsorption, neutron powder diffractio ...