Biogenic non-crystalline U(IV) revealed as major component in uranium ore deposits
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In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...
Uranium (U) is a ubiquitous element in the Earth's crust at similar to 2 ppm. In anoxic environments, soluble hexavalent uranium (U(VI)) is reduced and immobilized. The underlying reduction mechanism is unknown but likely of critical importance to explain ...
The production of radioisotope beams at the ISOLDE (Isotope Separator OnLine DEvice) facility at CERN is achieved by irradiating target materials (e.g. uranium carbides and metal foils) with protons. The materials are usually operated at temperatures above ...
Uranium (U) in situ bioremediation has been investigated as a cost-effective strategy to tackle U contamination in the subsurface. While uraninite was believed to be the only product of bioreduction, numerous studies have revealed that noncrystalline U(IV) ...
Knowledge of fundamental chemical properties of all environmentally relevant uranium species is essential to understand environmental uranium mobility and develop novel remediation strate-gies. A myriad of uranium(VI) and uranium(IV) compounds has been stu ...
The activation of small molecules is a paramount challenge in modern chemistry. The use of cheap and abundant molecules such as N2, H2, CO2, or CO as energy supplies or as precursors for fine chemicals production is highly desirable. In particular, the onl ...
Uranium (U) contamination of ground and surface waters poses an acute hazard on the ecosystem and human health. Since the discovery of microbial U(VI) reduction, U bioremediation has been explored as a promising and cost-effective method compared to tradit ...
Permeability is a key physical property across all spatial scales in the Earth’s crust and exerts significant control on the behaviour of Earth systems, with implications for natural hazards (e.g., earthquakes, slope instabilities, volcanic eruptions) and ...
A large fraction (47%) of the world's uranium is mined by a technique called “In Situ Recovery” (ISR). This mining technique involves the injection of a leaching fluid (acidic or alkaline) into a uranium-bearing aquifer and the pumping of the resulting sol ...