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Photocurrent Spectroscopy of Perovskite Layers and Solar Cells: A Sensitive Probe of Material Degradation

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Perovskite Solar Cells on the Way to Their Radiative Efficiency Limit - Insights Into a Success Story of High Open-Circuit Voltage and Low Recombination

Wolfgang Richard Tress

Inorganic-organic lead-halide perovskite solar cells have reached efficiencies above 22% within a few years of research. Achieved photovoltages of >1.2 V are outstanding for a material with a bandgap of 1.6 eV - in particular considering that it is solutio ...

Wiley-V C H Verlag Gmbh2017

We report the presence of defects in CH3NH3PbI3, which is one of the main factors that deteriorates the performance of perovskite solar cells. Although the efficiency of the perovskite solar cells has been improved by curing defects using various methods, ...

Royal Soc Chemistry2017

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Functionalized imidazolium iodide salts (ionic liquids) modified with -CH2-CH=CH2, -CH2C equivalent to CH, or -CH2C equivalent to N groups are applied as dopants in the synthesis of CH3NH3PbI3-type perovskites together with a fumigation step. Notably, a so ...

Wiley-Blackwell2017

Undoubtedly, perovskite solar cells have become a key player in 3rd generation photovoltaics over the last few years. Although it is only in 2012 that the first solid state perovskite solar cell was reported, power conversion efficiencies have increased so ...

EPFL2017

Interfacial Kinetics of Efficient Perovskite Solar Cells

Shaik Mohammed Zakeeruddin, Michael Saliba, Pankaj Kumar Yadav, Daniel Prochowicz

Perovskite solar cells (PSCs) have immense potential for high power conversion efficiency with an ease of fabrication procedure. The fundamental understanding of interfacial kinetics in PSCs is crucial for further improving of their photovoltaic performanc ...

2017

Elucidating the role of chlorine in perovskite solar cells

Gang Wang, Ulf Anders Hagfeldt, Jingshan Luo, Xiaoyu Zhang, Yi Ding, Di Zhang, Li Fan

It has been proposed that introducing the chlorine anion into a CH3NH3PbI3 perovskite material can substantially improve the materials properties as well as the solar cell performance. To elucidate the role of chlorine in perovskite solar cells (PSCs), her ...

Royal Society of Chemistry2017

Incorporation of Counter Ions in Organic Molecules: New Strategy in Developing Dopant-Free Hole Transport Materials for Efficient Mixed-Ion Perovskite Solar Cells

Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Lin Yang, Jiahuan Zhang, Monica Marcela Lira Cantu, Liang Wang

Hole transport matertial (HTM) as charge selective layer in perovskite solar cells (PSCs) plays an important role in achieving high power conversion efficiency (PCE). It is known that the dopants and additives are necessary in the HTM in order to improve t ...

Wiley-V C H Verlag Gmbh2017

The presence of voids in perovskite solar cells influences the efficiency because of accelerated charge recombination. The induced electric field near voids due to band bending attracts photogenerated electrons and holes toward the voids, leading to carrie ...

Amer Chemical Soc2017

Perovskite/silicon tandem solar cells: marriage of convenience or true love story? - An overview

Christophe Ballif, Björn Niesen, Jérémie Werner

Perovskite/silicon tandem solar cells have reached efﬁciencies above 25% in just about three years of development, mostly driven by the rapid progress made in the perovskite solar cell research ﬁeld. This review aims to give an overview of the achievements ...

2017

A wire shaped coaxial photovoltaic solar cell

Michael Graetzel, Mohammad Khaja Nazeeruddin, Carlos Perez, Mohammad Ibrahim Dar

A wire shaped coaxial photovoltaic solar cell comprising: a conductive core wire shaped support (401), a nanostructured semiconductor scaffold layer (402), one or more successive perovskite layers (403), an optionally provided hole transporting material la ...

2017