Interpretation of x-ray absorption spectroscopy in the presence of surface hybridization
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We report the synthesis of atomically monodisperse thiol-protected silver nanoclusters Ag-44(SR)(30), (SR = 5-mercapto-2-nitrobenzoic acid) in which the product nanocluster is highly stable in contrast to previous preparation methods. The method is on ...
This study reports visible light sensitive ZrNO and ZrNO-Ag polyester samples prepared by sputtering in an Ar/N-2/O-2 atmosphere leading to Escherichia coil bacterial inactivation. The bacterial inactivation by ZrNO avoids the increasing environmental conc ...
In this study visible light active iodine doped titanium dioxide samples prepared by sol-gel method were investigated. Photocatalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray fluorescence spectroscopy (XF ...
We explore the local electronic signatures of molecular adsorption at coordinatively unsaturated binding sites in the metal-organic framework Mg-MOF-74 using X-ray spectroscopy and first-principles calculations. In situ measurements at the Mg K-edge reveal ...
2013
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Solid-state processes of introducing oxygen vacancies and transference of fluorine to n-TiO2 nanoparticles by co-milling with poly(tetrafluoroethylene) (PTFE) powder were examined by diffuse reflectance spectroscopy (DRS) of UV, visual, near- and mid-IR re ...
2012
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We perform quantum mechanics/molecular mechanics molecular dynamics simulations on the Pt-2(P2O5H2)(4) (abbreviated PtPOP) complex; in water, dimethylformamide and ethanol. These are used to calculate the ground state X-ray absorption spectrum of the ...
2012
One central aim of nanotechnology is the creation and exploitation of nanostructured materials with pre-programmed architecture and properties. The fabrication of functional nanostructures relies on versatile protocols of synthetic chemistry enabling the p ...
EPFL2012
This thesis presents two applications of 2,2'-bipyridine (bipy) derivatives, the first involves their use as stabilizers for nanoparticle (NP) catalysts and the second is concerned with the use of bipy ligands for ruthenium dye molecules applied in dye sen ...
EPFL2011
Nanocomposite coatings composed of two phases with atomically sharp phase boundaries, show interesting mechanical properties. These properties are often originating from their high interface to volume ratio. Composites of nanocrystalline titanium nitride ( ...
Evidence is presented for the RF pretreatment of polyester enhances the TiO2 coating generation of oxidative species/radicals under a low level actinic light irradiation. After 30 min RF-plasma pretreatment of the polyester samples, the fastest bacterial i ...