Significance of pi-bridge contribution in pyrido[3,4-b]pyrazine featured D-A-pi-A organic dyes for dye-sensitized solar cells
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During millions of years of evolution, all creatures have found their ways of harvesting, storing and utilizing the energy coming from the sun. Plants use photosynthesis to convert carbon dioxide to glucose. With a low efficiency of only 3%, plants still c ...
meso-Substituted boron-dipyrromethene (BODIPY) dyes are a puzzling class of molecules, which feature contrasting emissive behaviors. The full mechanistic picture for these distinctive properties is still missing. Using static and dynamic excited state comp ...
The power conversion efficiency of a dye-sensitized solar cell with tailored squaraine dye enhanced by 47%, due to Forster resonance energy transfer from CdSe quantum dots to the squaraine dye. The incident photons to collection efficiency of electrons ind ...
We report the design, synthesis and computational investigation of a class of Ru(II)-dyes based on mixed bipyridine ligands for use in dye-sensitized solar cells. These dyes are designed to preserve the optimal anchoring mode of the prototypical N719 sensi ...
An in-situ modulated photocurrent technique to study kinetics of dye adsorption and to determine binding constants of dye molecules on the TiO 2 surface is presented. An AC-photocurrent signal is measured, when a TiO2 electrode is in contact with the dye b ...
Tools that assess the limitations of dye sensitized solar cells (DSSCs) made with new materials are critical for progress. Measuring the transient electrical signals (voltage or current) after optically perturbing a DSSC is an approach which can give infor ...
We present the photoelectrochemical properties of dye-sensitized solar cells using natural pigments containing betalains and anthocyanins as sensitizers. The dyes extracted from grape, mulberry, blackberry, red Sicilian orange, Sicilian prickly pear, eggpl ...
Photoinduced mol. rearrangements are important in daily events essential for life such as visual perception and photo-protection of light harvesting complexes in plants. In this study we demonstrate that similar photorearrangements appear in an analogous t ...
Seven unsymmetrical heptamethine dyes with carboxylic acid functionality were synthesized and characterized. These near-infrared dyes exhibit outstanding photophysical properties depending on their heterocyclic moieties and molecular structure. As proof of ...
We propose a passive factor, autocatalytic activity of some semiconductors (SnO2, WO3), for the loss of efficiency in dye-sensitized solar cells. On one hand, in the photoanode, SnO2 (or WO3) functions as a semiconductor to collect the photoelectrons that ...